Three potential techniques for texturing commercial multicrystalline silicon solar cells are compared on the basis of reflectance measurements. Wet acidic texturing, which would be the least costly to implement, produces a modest improvement in reflection before antirflection coating and encapsulation, whereas maskless reactiveion etching texturing, and especially masked reactive-ion etched 'pyramids', generate a larger gain in absorption. After antireflection coating and encapsulation however, the differences between the methods are reduced. Short-circuit current measurements on wet acidic textured cells reveal that there is a significant additional current gain above that expected from the reduced reflection. This is attributed to both light-trapping and oblique coupling of incident light into the cell, resulting in generation closer to the junction.

Highly sensitive and selective label free devices for real-time identification of specific biomarkers are expected to significantly impact the biosensing field. The ability of plasmonic systems to confine the light in nanometer volume and to manipulate it by tuning the size, shape and material features of the nanostructures, makes these systems promising candidates for biomedical devices. In this work we demonstrate the engineered sensing capabilities of a compact array of 3D metal dielectric core-shell chiral metamaterial. The intrinsic chirality of the nano-helices makes the system circular polarization dependent and unaffected by the background interferences, allowing to work even in complex environment. The core-shell architecture enhances the sensing properties of the chiral metamaterial on both in the far and near field, also offering a large surface to molecular immobilization. With our system we recorded sensitivity of about 800nm/RIU and FOM= 1276 RIU -1 . The sensing abilities of the system is demonstrated with the detection of the TAR DNA-binding protein 43 (TDP-43), a critical biomarker for the screening of neurodegenerative diseases. In particular, the sensor was tested in different environments, such as human serum, with concentrations ranging from 1pM down to 10fM, opening new perspectives for novel diagnostic tools.

Fine control of the chiral light-matter interaction at the nanoscale, by exploiting designed metamaterial architecture, represents a cutting-edge craft in the field of biosensing, quantum, and classic nanophotonics. Recently, artificially engineered 3D nanohelices demonstrate programmable wide chiroptical properties by tuning materials and architecture, but fundamental diffractive aspects that are at the origin of chiral resonances still remain elusive. Here, a novel concept of a 3D chiral metacrystal, where the chiroptical properties are finely tuned by in-plane and out-of-plane diffractive coupling, is proposed. Different chiral dipolar modes can be excited along the helix arms, generating far field optical resonances and radiation pattern with in-plane side lobes, and suggesting that a combination of efficient dipole excitation and diffractive coupling matching controls the collective oscillations among the neighbor helices. The proposed concept of compact chiral metacrystal can be suitable for integration with quantum emitters and open perspectives in novel schemes of enantiomeric detection.

Sustainable growth, environmental preservation, and improvement of life quality are strategic fields of worldwide interest and cornerstones of international policies. Humanity health and prosperity are closely related to our present choices on sustainable development. The main sources of pollution concern industry, including mining, chemical companies, and refineries, wastewater treatment; and consumers themselves. In order to guide and evaluate the effects of environmental policies, diffuse monitoring campaigns and detailed (big) data analyses are needed. In this respect, the development and availability of innovative sensor platforms for field analysis and remote sensing are of crucial relevance. In this review, we provide an overview of the area, analyzing the major needs, available technologies, novel approaches, and perspectives. Among environmental pollutants that threaten the biosphere, we focus on inorganic and organic contaminants, which affect air and water quality. We describe the technologies for their assessment in the environment and then draw some conclusions and mention future perspectives opened by the integration of sensing technologies with robotics and the Internet of Things. Without the ambition to be exhaustive in such a rapidly growing field, this review is intended as a support for researchers and stakeholders looking for current, state-of-the-art, and key enabling technologies for environmental monitoring.