A pronounced negative carbon-isotope (delta13C) excursion of approximately 5-7 per thousand (refs 1-7) indicates the occurrence of a significant perturbation to the global carbon cycle during the Early Jurassic period (early Toarcian age, approximately 183 million years ago). The rapid release of 12C-enriched biogenic methane as a result of continental-shelf methane hydrate dissociation has been put forward as a possible explanation for this observation. Here we report high-resolution organic carbon-isotope data from well-preserved mudrocks in Yorkshire, UK, which demonstrate that the carbon-isotope excursion occurred in three abrupt stages, each showing a shift of -2 per thousand to -3 per thousand. Spectral analysis of these carbon-isotope measurements and of high-resolution carbonate abundance data reveals a regular cyclicity. We interpret these results as providing strong evidence that methane release proceeded in three rapid pulses and that these pulses were controlled by astronomically forced changes in climate, superimposed upon longer-term global warming. We also find that the first two pulses of methane release each coincided with the extinction of a large proportion of marine species.
The term Anthropocene, proposed and increasingly employed to denote the current interval of anthropogenic global environmental change, may be discussed on stratigraphic grounds. A case can be made for its consideration as a formal epoch in that, since the start of the Industrial Revolution, Earth has endured changes sufficient to leave a global stratigraphic signature distinct from that of the Holocene or of previous Pleistocene interglacial phases, encompassing novel biotic, sedimentary, and geochemical change. These changes, although likely only in their initial phases, are sufficiently distinct and robustly established for suggestions of a Holocene-Anthropocene boundary in the recent historical past to be geologically reasonable. The boundary may be defined either via Global Stratigraphic Section and Point ("golden spike") locations or by adopting a numerical date. Formal adoption of this term in the near future will largely depend on its utility, particularly to earth scientists working on late Holocene successions. This datum, from the perspective of the far future, will most probably approximate a distinctive stratigraphic boundary.
The long-term stability of Earth's climate throughout the Phanerozoic stands in marked contrast to the dramatic fluctuations that have taken place on time scales as short as a few years, reflecting the high efficiency of longer-term climate regulation through negative feedbacks. A fundamental mechanism is thought to involve control of CO 2 in the ocean-atmosphere system through continental weathering, although unambiguous, high-resolution data supporting this hypothesis have hitherto not been available. Organic-rich mudrocks from Yorkshire, England, which were deposited during the Toarcian oceanic anoxic event (ca. 181 Ma, Early Jurassic), contain evidence of an exceptionally large excursion in the 187 Os/ 188 Os ratio of contemporaneous seawater, from ϳ0.4 to ϳ1.0. The most likely explanation for this excursion is that it resulted from a transient increase in global continental weathering rates of ϳ400%-800%. The Os isotope excursion coincided with a well-documented global ␦ 13 C excursion of ؊6‰ that affected all the major biospheric reservoirs of the time. Higher mean global temperatures caused global chemical weathering rates to increase substantially, while, in turn, chemical weathering was very effective in reducing the elevated levels of atmospheric CO 2 and the high temperatures to preexcursion levels.Keywords: osmium, weathering, Toarcian, oceanic anoxic event, strontium, methane hydrate. of this manuscript, and the Natural Environment Research Council and the Open University for financial support. We are grateful for journal reviews provided by S.P. Hesselbo and an anonymous reviewer.
Rhenium and osmium isotope and abundance data have been obtained on precisely-located samples from three suites of immature, organic-rich mudrocks from Jurassic coastal outcrops in England. The data provide precise and accurate whole-rock ages of 207±12 Ma, 181±13 Ma and 155±4.3 Ma for suites of Hettangian, Toarcian (exeratum Subzone) and Kimmeridgian (sensu anglico, wheatleyensis Subzone) samples. These new Re-Os ages are indistinguishable, within the assigned analytical uncertainties, from interpolated depositional ages estimated from published geological timescales, and establish the importance of the ReOs dating technique for chronostratigraphic studies. Early-diagenetic pyrite nodules possess levels of Re and Os which are ~1-2 orders of magnitude lower than in the enclosing organicrich mudrocks, indicating that these elements had already been removed from sediment pore waters at the time of nodule formation. Thus the Re-Os isotope system in these organic-rich mudrocks has been closed since, or from very soon after, the time of sediment deposition.Because most of the Re (98%+) and Os (95-99.8%+) in the mudrocks is shown to be hydrogenous, the 187 Os/ 188 Os (i) of the samples is interpreted to be that of contemporaneous seawater. The data thereby provide the first estimates of the Os isotope composition of Jurassic seawater. During the earliest Jurassic (Hettangian), the seawater 187 Os/ 188 Os ratio was extremely unradiogenic (~0.15); it had increased to ~0.8 at the end of the Early Jurassic (Toarcian) ~20 Ma later, while in the Late Jurassic (Kimmeridgian) the seawater 187 Os/ 188 Os ratio was ~0.59. The most likely explanation for the unradiogenic Os isotope composition of Hettangian seawater is that the contribution of unradiogenic Os to the oceans from the hydrothermal alteration of oceanic crust greatly exceeded the input of radiogenic Os from the continents at that time. This interpretation is in line with observations suggesting that global weathering rates were low in the Hettangian, and that increased hydrothermal and volcanic activity preceded the break-up of Pangea. The Re/Os ratios of Hettangian mudrocks (and by inference, of contemporaneous seawater) are similar to those of mudrocks deposited at later times during the Jurassic, and argues against the unradiogenic Os in Hettangian seawater being derived from extraterrestrial meteoritic sources.
The Anthropocene, an informal term used to signal the impact of collective human activity on biological, physical and chemical processes on the Earth system, is assessed using stratigraphic criteria. It is complex in time, space and process, and may be considered in terms of the scale, relative timing, duration and novelty of its various phenomena. The lithostratigraphic signal includes both direct components, such as urban constructions and man-made deposits, and indirect ones, such as sediment flux changes. Already widespread, these are producing a significant ‘event layer’, locally with considerable long-term preservation potential. Chemostratigraphic signals include new organic compounds, but are likely to be dominated by the effects of CO 2 release, particularly via acidification in the marine realm, and man-made radionuclides. The sequence stratigraphic signal is negligible to date, but may become geologically significant over centennial/millennial time scales. The rapidly growing biostratigraphic signal includes geologically novel aspects (the scale of globally transferred species) and geologically will have permanent effects.
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