Low cost pollution sensors have been widely publicized, in principle offering increased information on the distribution of air pollution and a democratization of air quality measurements to amateur users. We report a laboratory study of commonly-used electrochemical sensors and quantify a number of cross-interferences with other atmospheric chemicals, some of which become significant at typical suburban air pollution concentrations. We highlight that artefact signals from co-sampled pollutants such as CO2 can be greater than the electrochemical sensor signal generated by the measurand. We subsequently tested in ambient air, over a period of three weeks, twenty identical commercial sensor packages alongside standard measurements and report on the degree of agreement between references and sensors. We then explore potential experimental approaches to improve sensor performance, enhancing outputs from qualitative to quantitative, focusing on low cost VOC photoionization sensors. Careful signal handling, for example, was seen to improve limits of detection by one order of magnitude. The quantity, magnitude and complexity of analytical interferences that must be characterised to convert a signal into a quantitative observation, with known uncertainties, make standard individual parameter regression inappropriate. We show that one potential solution to this problem is the application of supervised machine learning approaches such as boosted regression trees and Gaussian processes emulation.

Advanced parametric financial instruments, like weather index insurance (WII) and risk contingency credit (RCC), support disaster-risk management and reduction in the world’s most disaster-prone regions. Simultaneously, satellite data that are capable of cross-checking rainfall estimates, the “standard dataset” to develop such financial safety nets, are gaining importance as complementary sources of information. This study concentrates on the analysis of satellite-derived multi-sensor soil moisture (ESA CCI, Version v04.2), the evapotranspiration-based Evaporative Stress Index (ESI), and CHIRPS (Climate Hazards Group InfraRed Precipitation with Station data) rainfall estimates in nine East African countries. Based on spatial correlation analysis, we found matching spatial/temporal patterns between all three datasets, with the highest correlation coefficient occurring between October and March. In large parts of Kenya, Ethiopia, and Somalia, we observed a lower (partly negative) correlation coefficient between June and August, which was likely caused by issues related to cloud cover and the volume scattering of microwaves in sandy, hot soils. Based on simple linear and logit regression analysis with annual, national maize yield estimates as the dependent variable, we found that, depending on the chosen period (averages per year, growing or harvesting months), there was added value (higher R-squared) if two or all three variables were combined. The ESI and soil moisture have the potential to close sensitive knowledge gaps between atmospheric moisture supply and the response of the land surface in operational parametric insurance projects. For the development and calibration of WII and RCC, this means that better proxies for historical and potential future drought impact can strengthen “drought narratives”, resulting in a better match between calculated payouts/credit repayment levels and the actual needs of smallholder farmers.

High mixing ratios of ozone along the shores of Lake Michigan have been a recurring theme over the last 40 years. Models continue to have difficulty in replicating ozone behavior in the region. Although emissions and chemistry may play a role in model performance, the complex meteorological setting of the relatively cold lake in the summer ozone season and the ability of the physical model to replicate this environment may contribute to air quality modeling errors. In this paper, several aspects of the physical atmosphere that may affect air quality, along with potential paths to improve the physical simulations, are broadly examined. The first topic is the consistent overwater overprediction of ozone. Although overwater measurements are scarce, special boat and ferry ozone measurements over the last 15 years have indicated consistent overprediction by models. The roles of model mixing and lake surface temperatures are examined in terms of changing stability over the lake. From an analysis of a 2009 case, it is tentatively concluded that excessive mixing in the meteorological model may lead to an underestimate of mixing in offline chemical models when different boundary layer mixing schemes are used. This is because the stable boundary layer shear, which is removed by mixing in the meteorological model, can no longer produce mixing when mixing is rediagnosed in the offline chemistry model. Second, air temperature has an important role in directly affecting chemistry and emissions. Land–water temperature contrasts are critical to lake and land breezes, which have an impact on mixing and transport. Here, satellite-derived skin temperatures are employed as a path to improve model temperature performance. It is concluded that land surface schemes that adjust moisture based on surface energetics are important in reducing temperature errors.

Development of clouds in space and time within numerical meteorological models as observed in nature is essential for producing an accurate representation of the physical atmosphere for input into air quality models. In this study, a new technique was developed to assimilate Geostationary Operational Environmental Satellite (GOES)-derived cloud fields into the Weather Research and Forecasting (WRF) meteorological model to improve the placement of clouds in space and time within the model. The simulations were performed on 36-, 12-, and 4-km grid-size domains covering the contiguous United States, the south-southeastern United States, and eastern Texas, respectively. The technique was tested over the month of August 2006. The results indicate that the assimilation technique significantly improves the agreement between the model-predicted and GOES-derived cloud fields. The daily average percentage increase in the cloud agreement was determined to be 14.02%, 11.29%, and 4.96% for the 36-, 12-, and 4-km domains, respectively. This was accomplished without degrading the model performance with respect to surface wind speed, temperature, and mixing ratio, which are important parameters for air quality applications; in some cases these variables were even slightly improved. The assimilation technique also produced improvements in the model-predicted precipitation and predicted downwelling shortwave radiation reaching the surface.

Abstract. Uncertain photolysis rates and emission inventory impair the accuracy of state-level ozone (O3) regulatory modeling. Past studies have separately used satellite-observed clouds to correct the model-predicted photolysis rates, or satellite-constrained top-down NOx emissions to identify and reduce uncertainties in bottom-up NOx emissions. However, the joint application of multiple satellite-derived model inputs to improve O3 state implementation plan (SIP) modeling has rarely been explored. In this study, Geostationary Operational Environmental Satellite (GOES) observations of clouds are applied to derive the photolysis rates, replacing those used in Texas SIP modeling. This changes modeled O3 concentrations by up to 80 ppb and improves O3 simulations by reducing modeled normalized mean bias (NMB) and normalized mean error (NME) by up to 0.1. A sector-based discrete Kalman filter (DKF) inversion approach is incorporated with the Comprehensive Air Quality Model with extensions (CAMx)–decoupled direct method (DDM) model to adjust Texas NOx emissions using a high-resolution Ozone Monitoring Instrument (OMI) NO2 product. The discrepancy between OMI and CAMx NO2 vertical column densities (VCDs) is further reduced by increasing modeled NOx lifetime and adding an artificial amount of NO2 in the upper troposphere. The region-based DKF inversion suggests increasing NOx emissions by 10–50% in most regions, deteriorating the model performance in predicting ground NO2 and O3, while the sector-based DKF inversion tends to scale down area and nonroad NOx emissions by 50%, leading to a 2–5 ppb decrease in ground 8 h O3 predictions. Model performance in simulating ground NO2 and O3 are improved using sector-based inversion-constrained NOx emissions, with 0.25 and 0.04 reductions in NMBs and 0.13 and 0.04 reductions in NMEs, respectively. Using both GOES-derived photolysis rates and OMI-constrained NOx emissions together reduces modeled NMB and NME by 0.05, increases the model correlation with ground measurement in O3 simulations, and makes O3 more sensitive to NOx emissions in the O3 non-attainment areas.