The superconducting transmon qubit is a leading platform for quantum computing and quantum science. Building large, useful quantum systems based on transmon qubits will require significant improvements in qubit relaxation and coherence times, which are orders of magnitude shorter than limits imposed by bulk properties of the constituent materials. This indicates that relaxation likely originates from uncontrolled surfaces, interfaces, and contaminants. Previous efforts to improve qubit lifetimes have focused primarily on designs that minimize contributions from surfaces. However, significant improvements in the lifetime of two-dimensional transmon qubits have remained elusive for several years. Here, we fabricate two-dimensional transmon qubits that have both lifetimes and coherence times with dynamical decoupling exceeding 0.3 milliseconds by replacing niobium with tantalum in the device. We have observed increased lifetimes for seventeen devices, indicating that these material improvements are robust, paving the way for higher gate fidelities in multi-qubit processors.

Resistive switching offers a promising route to universal electronic memory, potentially replacing current technologies that are approaching their fundamental limits. In many cases switching originates from the reversible formation and dissolution of nanometre-scale conductive filaments, which constrain the motion of electrons, leading to the quantisation of device conductance into multiples of the fundamental unit of conductance, G0. Such quantum effects appear when the constriction diameter approaches the Fermi wavelength of the electron in the medium – typically several nanometres. Here we find that the conductance of silicon-rich silica (SiOx) resistive switches is quantised in half-integer multiples of G0. In contrast to other resistive switching systems this quantisation is intrinsic to SiOx, and is not due to drift of metallic ions. Half-integer quantisation is explained in terms of the filament structure and formation mechanism, which allows us to distinguish between systems that exhibit integer and half-integer quantisation.

Graphene on hydrogen terminated monolayer nanodiamond heterostructures provides a new way to improve carrier transport characteristics of the graphene, offering up to 60% improvement when compared with similar graphene on SiO2/Si substrates. These heterostructures offers excellent current-carrying abilities whilst offering the prospect of a fast, low cost and easy methodology for device applications. The use of ND monolayers is also a compatible technology for the support of large area graphene films. The nature of the C-H bonds between graphene and H-terminated NDs strongly influences the electronic character of the heterostructure, creating effective charge redistribution within the system. Field effect transistors (FETs) have been fabricated based on this novel herterostructure to demonstrate device characteristics and the potential of this approach.

Superconducting circuits extensively rely on the Josephson junction as a nonlinear electronic element for manipulating quantum information and mediating photon interactions. Despite continuing efforts in designing anharmonic Josephson circuits with improved coherence times, the best photon lifetimes have been demonstrated in microwave cavities. Nevertheless, architectures based on quantum memories need a qubit element for addressing these harmonic modules at the cost of introducing additional loss channels and limiting process fidelities. This work focuses on tailoring the oscillator Hilbert space to enable a direct Rabi drive on individual energy levels. For this purpose we implement a flux-tunable inductive coupling between two linear resonators using a superconducting quantum interference device. We dynamically activate a three-wave mixing process through parametric flux modulation in order to selectively address the lowest eigenstates as an isolated two-level system. Measuring the Wigner function confirms we can prepare arbitrary states confined in the single photon manifold, with measured coherence times limited by the oscillator intrinsic quality factor. This architectural shift in engineering oscillators with stimulated nonlinearity can be exploited for designing long-lived quantum modules and offers flexibility in studying non-equilibrium physics with photons in a field-programmable simulator.Quantized electromagnetic excitations in superconducting circuits have become a promising platform for processing quantum information 1 . A central piece to this hardware is the Josephson effect, which grants nonlinearity with negligible dissipation. Nonlinear mesoscopic oscillators have been attracting much interest in studying non-equilibrium physics 2 . Electrical circuits composed of Josephson junctions behave as quantum systems with discrete energy levels resembling artificial atoms 3 . Although the coherence properties of anharmonic Josephson circuits have been improving these past two decades, storing microwave photons in harmonic oscillators leads to significantly longer coherence times 4,5 . This promising development has launched efforts in building hardwareefficient architectures based on quantum memories 6,7 . Since it is impossible to selectively address individual transitions in a harmonic system, Josephson qubits are used for preparing and transferring quantum information with negative impact on coherence and gate fidelities. In this work we present a new paradigm in exploiting the Josephson effect to perform logical operations directly on the oscillator Hilbert space using a dynamically activated nonlinearity.The key concept behind this experiment is to engineer a three-wave interaction between the electromagnetic modes of two linear oscillators, which we refer to as logical and blockade oscillator (Fig. 1A). Parametrically modulating the interaction amplitude stimulates the conversion of two logical photons into one blockade photon and vice-versa. Provided the conversion rate is larger than the oscil...