In this work, Cu–Sn–TiO2 composite coatings were electrochemically obtained from a sulfate bath containing 0–10 g/L of TiO2 nanoparticles. The effect of TiO2 particles on kinetics of cathodic electrodeposition has been studied by linear sweep voltammetry and chronopotentiometry. As compared to the Cu–Sn alloy, the Cu–Sn–TiO2 composite coatings show rougher surfaces with TiO2 agglomerates embedded in the metal matrix. The highest average amount of included TiO2 is 1.7 wt.%, in the case of the bath containing 5 g/L thereof. Composite coatings showed significantly improved antibacterial properties towards E. coli ATCC 8739 bacteria as compared to the Cu–Sn coatings of the same composition. Such improvement has been connected with the corrosion resistance of the composites studied by linear polarization and electrochemical impedance spectroscopy. In the bacterial media and 3% NaCl solutions, Cu–Sn–TiO2 composite coatings have lower corrosion resistance as compared to Cu–Sn alloys, which is caused by the nonuniformity of the surface.
The article presents the possibility of increasing the water-resistance of gypsum binders obtained based on synthetic gypsum by introducing additives derived from industrial wastes. Regularities were obtained for the influence of the type and amount of additives on the water-gypsum ratio, strength indicators, and water resistance of high-strength gypsum binder. The introduction of a single-component additive to improve water resistance does not have a significant effect. Complex additives based on Portland cement, granulated blast-furnace slag, electric steel-smelting slag, expanded clay dust and granite screenings of various fractions have been developed that make the maximum contribution to improving the water resistance of a high-strength gypsum binder based on synthetic calcium sulfate dihydrate, which made it possible to increase the water-resistance coefficient from 0.39 to 0.82.
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