Additive manufacturing, especially in the form of 3D printing, offers the exciting possibility of generating heterogeneous articles with precisely controlled internal microstructure. One area in which this feature can be of significant advantage is in diffusion control, specifically in the design and fabrication of microstructures which optimize the rate of transport of a solute to and from a contained fluid. In this work we focus on the use of flakes as diffusion-control agents and study computationally and theoretically the effect of orientation on the barrier properties of flake-filled composites. We conducted over 1500 simulations in two-dimensional, doubly-periodic unit cells each containing up to 3000 individual flake cross-sections which are randomly placed and with their axes forming an angle ( π 2 θ − ) with the direction of macroscopic diffusion. We consider long-flake systems of aspect ratio ( α ) 100 and 1000, from the dilute ( 0.01 αϕ = ) and into the concentrated ( 40 αϕ = ) regime. Based on the rotation properties of the diffusivity tensor, we derive a model which is capable of accurately reproducing all computational results ( 0.01 40 αϕ < < and 0 π 2 θ < < ). The model requires as inputs the two principal diffusivities of the composite, normal and parallel to the flake axis. In this respect, we find the models of Lape et al. [1] and Nielsen [2] form an excellent combination.Both our model and our computational data predict that at 0 θ > the quadratic dependence of the Barrier Improvement Factor (BIF) on ( αϕ ) is lost, with the BIF approaching a plateau at higher values of ( αϕ ). This plateau is lower as ( θ ) increases. We derive analytical estimates of this maximum achievable BIF at each level of misalignment; these are also shown to be in excellent agreement with the computational results. Finally we show that our computational results and model are in agreement with experimental evidence at small values of ( θ ).
This direct numerical study investigated the effect of orientational randomness on the barrier properties of flake-filled composites. Over 2500 simulations have been conducted in two-dimensional, doubly periodic unit cells, each containing 500 individual flake cross-sections which, besides being spatially random, assume random orientations within an interval [−ɛ, +ɛ] ([Formula: see text]). We consider long flake systems (aspect ratio α = 50, 100, and 1000) from the dilute (αϕ = 0.01) to the concentrated (αϕ = 15) regime, where (ϕ) is the flake volume fraction. At each (ɛ) and (αϕ), several realizations are generated. At each of those, the steady-state diffusion equation is solved, the mass flux across a boundary normal to the diffusion direction is computed and an effective diffusivity Deff calculated from Fick’s Law. The computational results for Deff are analyzed and the effects of (ɛ) and (αϕ) are quantified. These differ in the dilute (αϕ < 1) and in the concentrated regimes (1 < αϕ < 15). In the dilute regime, the barrier improvement factor is a linear function of (ɛ) and a power function of (αϕ), with the exponent (∼1.07) independent of orientation. In concentrated systems, we find that for aligned flakes or flakes showing small deviations from perfect alignment, the barrier improvement factor approaches the quadratic dependence on (αϕ) predicted by theory. However, the power exponent is found to decrease as (ɛ) increases, from 1.71 in the aligned system (ɛ = 0) to ∼0.9 in the fully random system (ɛ = π/2). We propose a scaling which incorporates the effects of both (αϕ) and (ɛ) on the barrier improvement factor, resulting in a master curve for all (αϕ) and (ɛ). Our results suggest that the anticipated barrier property improvement may not be realized if the flake orientations exhibit a significant scatter around the desired direction.
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