Summary The magnetic anisotropy exhibited by ferrofluid-impregnated samples serves as a proxy for their pore fabrics, and is therefore known as magnetic pore fabric. Empirically, the orientation of the maximum susceptibility indicates the average pore elongation direction, and predicts the preferred flow direction. Further, correlations exist between the degree and shape of magnetic anisotropy and the pores’ axial ratio and shape, and between the degrees of magnetic and permeability anisotropies. Despite its potential, the method has been rarely used, likely because the large variability in reported empirical relationships compromises interpretation. Recent work identified an additional contribution of distribution anisotropy, related to the arrangement of the pores, and a strong dependence of anisotropy parameters on the ferrofluid type and concentration, partly explaining the variability. Here, an additional effect is shown; the effective susceptibility of the ferrofluid depends on the measurement frequency, so that the resulting anisotropy depends on measurement conditions. Using synthetic samples with known void geometry and ferrofluids with known susceptibility (4.04 SI and 1.38 SI for EMG705 and EMG909, respectively), magnetic measurements at frequencies from 500 Hz to 512 kHz are compared to numerical predictions. Measurements show a strong frequency-dependence, especially for EMG705, leading to large discrepancies between measured and calculated anisotropy degrees. We also observe artefacts related to the interaction of ferrofluid with its seal, and the aggregation of particles over time. The results presented here provide the basis for a robust and quantitative interpretation of magnetic pore fabrics in future studies, and allow for re-interpretation of previous results provided that the ferrofluid properties and measurement conditions are known. We recommend that experimental settings are selected to ensure a high intrinsic susceptibility of the fluid, and that the effective susceptibility of the fluid at measurement conditions is reported in future studies.

Abstract. Numerous studies have revealed genetic similarities between Tethyan ophiolites and oceanic “proto-arc” sequences formed above nascent subduction zones. The Semail ophiolite (Oman–U.A.E.) in particular can be viewed as an analogue for this proto-arc crust. Though proto-arc magmatism and the mechanisms of subduction initiation are of great interest, insight is difficult to gain from drilling and limited surface outcrops in marine settings. In contrast, the 3–5 km thick upper-crustal succession of the Semail ophiolite, which is exposed in an oblique cross section, presents an opportunity to assess the architecture and volumes of different volcanic rocks that form during the proto-arc stage. To determine the distribution of the volcanic rocks and to aid exploration for the volcanogenic massive sulfide (VMS) deposits that they host, we have remapped the volcanic units of the Semail ophiolite by integrating new field observations, geochemical analyses, and geophysical interpretations with pre-existing geological maps. By linking the major-element compositions of the volcanic units to rock magnetic properties, we were able to use aeromagnetic data to infer the extension of each outcropping unit below sedimentary cover, resulting in a new map showing 2100 km2 of upper-crustal bedrock. Whereas earlier maps distinguished two main volcanostratigraphic units, we have distinguished four, recording the progression from early spreading-axis basalts (Geotimes), through axial to off-axial depleted basalts (Lasail), to post-axial tholeiites (Tholeiitic Alley), and finally boninites (Boninitic Alley). Geotimes (“Phase 1”) axial dykes and lavas make up ∼55 vol % of the Semail upper crust, whereas post-axial (“Phase 2”) lavas constitute the remaining ∼45 vol % and ubiquitously cover the underlying axial crust. Highly depleted boninitic members of the Lasail unit locally occur within and directly atop the axial sequence, marking an earlier onset of boninitic magmatism than previously known for the ophiolite. The vast majority of the Semail boninites, however, belong to the Boninitic Alley unit and occur as discontinuous accumulations up to 2 km thick at the top of the ophiolite sequence and constitute ∼15 vol % of the upper crust. The new map provides a basis for targeted exploration of the gold-bearing VMS deposits hosted by these boninites. The thickest boninite accumulations occur in the Fizh block, where magma ascent occurred along crustal-scale faults that are connected to shear zones in the underlying mantle rocks, which in turn are associated with economic chromitite deposits. Locating major boninite feeder zones may thus be an indirect means to explore for chromitites in the underlying mantle.

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Empirical relationships between magnetic fabrics and deformation have long served as a fast and efficient way to interpret rock textures. Understanding the single crystal magnetic properties of all minerals that contribute to the magnetic anisotropy of a rock, allows for more reliable and quantitative texture interpretation. Integrating information of single crystal properties with a determination whether or not mineral and magnetic fabrics are parallel may yield additional information about the texture type. Models based on textures and single crystal anisotropies help assess how the individual minerals in a rock contribute to the rock's anisotropy, and how the individual anisotropy contributions interfere with each other. For this, accurate and reliable single crystal data need to be available. This review paper discusses magnetic anisotropy in single crystals of the most common rock-forming minerals, silicates and carbonates, in relation to their mineralogy and chemical composition. The most important ferromagnetic minerals and their anisotropy are also discussed. This compilation and summary will hopefully lead to a deeper understanding of the sources of magnetic anisotropy in rocks, and improve the interpretation of magnetic fabrics in future structural and tectonic studies.

Pore fabrics define physical properties of a rock, such as permeability and elasticity, both of which are important to many geological, hydrological, and environmental applications. Minerals and hence pores are often preferentially aligned, leading to anisotropy of physical properties and preferred flow directions. Preferred flow paths are defined by the shape and arrangement of pores, and a characterization of this pore fabric forms the basis for prediction of fluid flow directions. Magnetic pore fabrics (MPFs), that is, magnetic anisotropy measurements on ferrofluid-impregnated samples, are a promising and fast way to characterize the pore fabric of connected pores in 3-D, while analyzing a large number of pores with sizes down to 10 nm, without the need for any a priori knowledge about fabric orientation. Empirical relationships suggest that the MPF is related to the pore shape and orientation and approximates permeability anisotropy. This study uses models including shape and distribution anisotropy to better understand and quantify MPFs, using simple pore shapes and pore assemblies measured in previous studies. The results obtained in this study show that (1) shape anisotropy reliably predicts the MPF of single pores, (2) both shape and distribution anisotropy are needed to predict MPFs of pore assemblies, and (3) the anisotropy parameters P, L, and F are affected by the intrinsic susceptibility of the ferrofluid in addition to pore geometry. These findings can help explain some of the variability in empirical relationships and are an important step toward a quantitative understanding and application of MPFs in geological and environmental studies.Plain Language Summary To produce clean drinking water, use geothermal energy, or control contamination, it is necessary to understand how fluids flow underground. They have to find their way from pore to pore. As soon as pores are elongated or flattened, fluids can move more easily and thus faster in some directions than others. It is desirable to predict such preferred flow directions, and a good description of the pore space is needed to do so. Many methods exist to characterize the pore space, and one of these is based on the directional dependence of magnetic properties of samples, whose pores have been filled with strongly magnetic fluid. The method is efficient and promising, but unfortunately, it is not well understood how the magnetic data reflects the details of the pore space. The models developed here help define and quantify the factors controlling the observable magnetic properties. This understanding will make the method more applicable and useful in geothermal, hydrological, and environmental applications.

Pyroxenes constitute an important component in mafic igneous and metamorphic rocks. They often possess a prismatic habit, and their long axis, the crystallographic c axis, helps define a lineation in a textured rock. Anisotropy of magnetic susceptibility (AMS) serves as a fabric indicator in igneous and metamorphic rocks. If a rock's AMS is carried by pyroxenes, it can be related to their crystallographic preferred orientation and degree of alignment. This requires knowing the intrinsic AMS of pyroxene single crystals. This study provides a comprehensive low-field and high-field AMS investigation of chemically diverse orthopyroxene and clinopyroxene crystals in relation to crystal structure, chemical composition, oxidation state of Fe, and the possible presence of ferromagnetic inclusions. The paramagnetic anisotropy, extracted from high-field data, shows clear relationships to crystallographic directions and Fe concentration both in clinopyroxene and orthopyroxene. In the diopside-augite series, the intermediate susceptibility is parallel to b, and the maximum is at 45°to the c axis. In aegirine, the intermediate axis remains parallel to b, while the maximum susceptibility is parallel to c. The AMS of spodumene depends on Fe concentration. In enstatite, the maximum susceptibility aligns with c and the minimum with b, and in the case of hypersthene, the maximum susceptibility is normal to the exsolution lamellae. Magnetite inclusions within augite possess a ferromagnetic anisotropy with consistent orientation of the principal susceptibilities, which dominates the low-field anisotropy. These results provide better understanding of magnetic anisotropy in pyroxenes and form a solid basis for interpretation of magnetic fabrics in pyroxene-bearing rocks.

Abstract. Recent studies have revealed genetic similarities between Tethyan ophiolites and oceanic proto-arc sequences formed above nascent subduction zones. The Semail ophiolite (Oman–U.A.E.) in particular can be viewed as an analogue for this proto-arc crust. Though proto-arc magmatism and the mechanisms of subduction-initiation are of great interest, insight is difficult to gain from drilling and limited surface outcrops in submarine fore-arcs. In contrast, the Semail ophiolite, in which the 3–5 km thick upper-crustal succession is exposed in an oblique cross-section, presents an opportunity to assess the architecture and volumes of different volcanic rocks that form during the protoarc stage. To determine the distribution of the volcanic rocks and to aid exploration for the volcanogenic massive sulphide (VMS) deposits that they host, we have re-mapped the volcanic units of the Semail ophiolite by integrating new field observations, geochemical analyses and geophysical interpretations with pre-existing geological maps. By linking the major element compositions of the volcanic units to rock magnetic properties, we were able to use aeromagnetic data to infer the extension of each outcropping unit below sedimentary cover, resulting in in a new map showing 2100 km2 of upper-crustal bedrock. Whereas earlier maps distinguished two main volcanostratigraphic units, we have distinguished four, recording the progression from early spreading-axis basalts (Geotimes) through to axial to off-axial depleted basalts (Lasail), to post-axial tholeiites (Tholeiitic Alley) and finally boninites (Boninitic Alley). Geotimes (Phase 1) axial dykes and lavas make up ~55 vol% of the Semail upper crust, whereas post-axial (Phase 2) lavas constitute the remaining ~ 45 vol % and ubiquitously cover the underlying axial crust. The Semail boninites occur as discontinuous accumulations up to 2 km thick at the top of the sequence and constitute ~ 15 vol % of the upper crust. The new map provides a basis for targeted exploration of the gold-bearing VMS deposits hosted by these boninites. The thickest boninite accumulations occur in the Fizh block, where magma ascent occurred along crustal-scale faults that are connected to shear zones in the underlying mantle rocks, which in turn are associated with economic chromitite deposits. Locating major boninite feeder zones may thus be an indirect means to explore for chromitites in the underlying mantle.