A selected series of dipole functionalized triphenylene-based discotic liquid crystals (DLCs) was synthesized and investigated in a systematic way to reveal the phase behavior and molecular dynamics.
For the first time, the molecular mobility of two linear-shaped tetramethylated guanidinium triflate ionic liquid crystals (ILCs) having different lengths of alkyl chains was investigated using a combination of broadband dielectric spectroscopy (BDS) and specific heat spectroscopy (SHS). By self-assembly, these ILCs can form a hexagonal ordered mesophase besides plastic crystalline phases and the isotropic state. Three dielectric active processes were found using BDS for both samples. At low temperatures, a γ-process in the plastic crystalline state is observed which is assigned to localized fluctuations of methyl groups including nitrogen atoms in the guanidinium head. At higher temperatures but still in the plastic crystalline state, an α-process takes place. An α-process was detected using SHS but with a completely different temperature dependence of the relaxation times than that of the α-relaxation. This result is discussed in detail, and different molecular assignments of the processes are suggested. At even higher temperatures, electrical conductivity is detected and an increase in the DC conductivity by four orders of magnitude at the phase transition from the plastic crystalline to the hexagonal columnar mesophase is found. This result is traced to a change in the charge transport mechanism from a delocalized electron hopping in the stacked aromatic systems (in the plastic phase) to one dominated by an ionic conduction in the quasi-1D ion channels formed along the supermolecular columns in the ILC hexagonal mesophases.
The phase behavior of two unsymmetrical triphenylene crown ether-based columnar liquid crystals bearing different lengths of alkyl chains, KAL465 and KAL468, was investigated using differential scanning calorimetry (DSC). A plastic crystalline (Cry), a columnar liquid crystalline (Col h ), and an isotropic phase were observed along with two glass transitions in the Cry phase. The molecular mobility of the KAL compounds was further studied by a combination of broadband dielectric spectroscopy (BDS) and advanced calorimetric techniques. By the BDS investigations, three dielectric active relaxation processes were observed for both samples. At low temperatures, a γ-process in the Cry state was detected and is assigned to the localized fluctuations taking place in the alkyl chains. An α 2 -process takes place at higher temperatures in the Cry phase. An α 3 -process was found in the Col h mesophase. The advanced calorimetric techniques consist of fast scanning calorimetry (FSC) and specific heat spectroscopy employing temperature-modulated DSC and FSC. The advanced calorimetric investigations revealed that besides the α 2 -process in agreement with BDS, there is a second dynamic glass transition (α 1 -process), which is not observed by dielectric spectroscopy. The results are in good agreement with the glass transitions detected by DSC for this process. The temperature dependences of the relaxation rates of the α 1 -, α 2 -, and α 3 -processes are all different. Therefore, different molecular assignments for the relaxation processes are proposed. In addition to the relaxation processes, a conductivity contribution was explored by BDS for both KAL compounds. The conductivity contribution appears in both Cry and Col h phases, where the conductivity increases by ca. 1 order of magnitude at phase transition from the Cry to the hexagonal phase.
Crown ethers and their derivatives are versatile building blocks for the design of supramolecular materials. They can be functionalized at will and are well known for their abilities to complex with alkali cations. Here, we show that emissive lanthanide free hybrid materials can be generated by using such building blocks. The organic tribenzo[18]crown-6 central core was functionalized via six-fold Suzuki cross-coupling as a key reaction with three o-terphenyl units which could be converted into their corresponding triphenylenes by the Scholl reaction, leading to novel liquid-crystalline columnar materials. Selected tribenzo[18]crown-6 o-terphenyls could interact with emissive ternary metal cluster compound salts to generate hybrid materials combining the properties of both moieties. Due to synergistic effects and despite the anisometry of the cluster compounds, individual properties such as liquid-crystalline phase stability of the organic part and emission abilities of its inorganic counter-part are enhanced in the hybrid compounds.
A series of tetraguanidinium tetraphenylethene (TPE) arylsulfonates with different chain lengths was prepared via ionic self-assembly of tetraguanidinium TPE chloride and the respective methyl arylsulfonates. Liquid crystalline properties were studied by differential scanning calorimetry, polarizing optical microscopy and X-ray diffraction. Tetraguanidinium TPE arylsulfonates with chain lengths of C8 -C12 displayed hexagonal columnar mesophases over a broad temperature range, while derivatives with longer chains showed oblique columnar phases. In solution all compounds displayed aggregation-induced emission behaviour. Temperature-dependent luminescence spectra of the bulk phase of the tetraguanidinium TPE arylsulfonate with C14 side chains revealed a strong luminescence both in the solid state and the oblique columnar mesophase. The emission behaviour was rationalized by a unique combination of restriction of intramolecular rotation of the TPE core, Coulomb interaction between the guanidinium cations and − interactions of the anionic arylsulfonate moieties.
Aminocyclopropenium ions have raised much attention as organocatalysts and redox active polymers. However, the self‐assembly of amphiphilic aminocyclopropenium ions remains challenging. The first deltic ionic liquid crystals based on aminocyclopropenium ions have been developed. Differential scanning calorimetry, polarizing optical microscopy and X‐ray diffraction provided insight into the unique self‐assembly and nanosegregation of these liquid crystals. While the combination of small headgroups with linear p‐alkoxyphenyl units led to bilayer‐type smectic mesophases, wedge‐shaped units resulted in columnar mesophases. Upon increasing the size and polyphilicity of the aminocyclopropenium headgroup, a lamellar phase was formed.
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