Two optical beams of the same frequency but different wave vectors propagating through a homogeneous dielectric medium can exchange photons with each other and/or undergo mutually induced phase shifts as a result of a stimulated Rayleigh emission underpinning the coupling term of the Poynting theorem. Quadrature states of the same optical wave exchange power as they propagate through a homogeneous and linear dielectric medium. Consequently, coupling of photons between two optical waveguides takes place in the shared cladding region.

Three physical elements are missing from the conventional formalism of quantum photonics: (1) the quantum Rayleigh spontaneous and stimulated emissions; (2) the unavoidable parametric amplification; and (3) the mixed time-frequency spectral structure of a photonic field which specifies its duration or spatial extent. As a single photon enters a dielectric medium, the quantum Rayleigh scattering prevents it from propagating in a straight-line, thereby destroying any possible entanglement. A pure dynamic and coherent state composed of two consecutive number states, delivers the correct expectation values for the number of photons carried by a photonic wave front, its complex optical field, and phase quadratures. The intrinsic longitudinal and lateral field profiles associated with a group of photons for any instantaneous number of photons are independent of the source. These photonic properties enable a step-by-step analysis of the correlation functions characterizing counting of coincident numbers of photons or intensities with unity visibility interference, spanning the classical and quantum optic regimes.

An approximation-free and fully quantum optic formalism for parametric processes is presented. Phase-dependent gain coefficients and related phase-pulling effects are identified for quantum Rayleigh emission and the electro-optic conversion of photons providing parametric amplification in small scale integration of photonic devices. These mechanisms can be manipulated to deliver, simultaneously, sub-Poissonian distributions of photons as well as phase-dependent amplification in the same optical quadrature of a signal field.

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