The ability to control the interfacial properties in metal-oxide thin films through surface defect engineering is vital to fine tune their optoelectronic properties and thus their integration in novel optoelectronic devices. This is exemplified in photovoltaic devices based on organic, inorganic or hybrid technologies, where precise control of the charge transport properties through the interfacial layer is highly important for improving device performance. In this work, we study the effects of in situ annealing in nearly stoichiometric MoO x (x~3.0) thin-films deposited by reactive sputtering. We report on a work function increase of almost 2 eV after inducing in situ crystallization of the films at 500°C, resulting in the formation of a single crystalline α-MoO 3 overlaid by substoichiometric and highly disordered nanoaggregates. The surface nanoaggregates possess various electronic properties, such as a work function ranging from 5.5 eV up to 6.2 eV, as determined from low-energy electron microscopy studies. The crystalline underlayer possesses a work function greater than 6.3 eV, up to 6.9 eV, characteristic of a very clean and nearly defect-free MoO 3 . By combining electronic spectroscopies together with structural characterizations, this work addresses a novel method for tuning, and correlating, the optoelectronic properties and microstructure of device-relevant MoO x layers.
Crystalline molybdenum oxide layers as efficient and stable hole contacts in organic photovoltaic devices Ahmadpour, Mehrad; Cauduro, A. L. F.; Méthivier, C.; Kunert, B. ; Labanti, C.; Resel, R.; Engmann
In this letter, we report on the effect of oxygen partial pressure and sputtering power on amorphous DC-sputtered MoOx films. We observe abrupt changes in the optoelectronic properties of the reported films by increasing the oxygen partial pressure from 1.00 × 10−3 mbar to 1.37 × 10−3 mbar during the sputtering process. A strong impact on the electrical conductivity, varying from 1.6 × 10−5 S/cm to 3.22 S/cm, and on the absorption coefficient in the range of 0.6–3.0 eV is observed for the nearly stoichiometric MoO3.00 and for the sub-stoichiometric MoO2.57 films, respectively, without modifying significantly the microstructure of the studied films. The presence of states within the band gap due to the lack of oxygen is the most probable mechanism for generating a change in electrical conductivity as well as optical absorption in DC-sputtered MoOx. The large tuning range of the optoelectronic properties in these films holds strong promise for their implementation in optoelectronic devices.
Magnetic
materials offer an opportunity to overcome the scalability and energy
consumption limits affecting the semiconductor industry. New computational
device architectures, such as low-power solid state magnetic logic
and memory-in-logic devices, have been proposed which rely on the
unique properties of magnetic materials. Magnetic skyrmions, topologically
protected quasi-particles, are at the core of many of the newly proposed
spintronic devices. Many different materials systems have been shown
hosting ferromagnetic skyrmions at room temperature. However, a magnetic
field is a key ingredient to stabilize skyrmions, and this is not
desirable for applications, due to the poor scalability of active
components generating magnetic fields. Here we report the observation
of ferromagnetic skyrmions at room temperature and zero magnetic field,
stabilized through interlayer exchange coupling (IEC) between a reference magnet and a free magnet. Most
importantly, by tuning the strength of the IEC, we are able to tune
the skyrmion size and areal density. Our findings are relevant to
the development of skyrmion-based spintronic devices suitable for
general-use applications which go beyond modern nanoelectronics.
Bathocuproine (BCP) is a well-studied cathode interlayer in organic photovoltaic (OPV) devices, where it for standard device configurations has demonstrated improved electron extraction as well as exciton blocking properties, leading to high device efficiencies. For inverted devices, however, BCP interlayers has shown to lead to device failure, mainly due to the clustering of BCP molecules on indium tin oxide (ITO) surfaces, which is a significant problem during scale-up of the OPV devices. In this work, we introduce C
70
doped BCP thin films as cathode interlayers in inverted OPV devices. We demonstrate that the interlayer forms smooth films on ITO surfaces, resulting from the introduction of C
70
molecules into the BCP film, and that these films possess both improved electron extraction as well exciton blocking properties, as evidenced by electron-only devices and photoluminescence studies, respectively. Importantly, the improved cathode interlayers leads to well-functioning large area (100 mm
2
) devices, showing a device yield of 100%. This is in strong contrast to inverted devices based on pure BCP layers. These results are founded by the effective suppression of BCP clustering from C
70
, along with the electron transport and exciton blocking properties of the two materials, which thus presents a route for its integration as an interlayer material towards up-scaled inverted OPV devices.
In this letter, we demonstrate that improved low energy electron absorption is achieved by suppressing the crystallinity of chromium thin-films grown on W[110], which points to a promising route for achieving highly efficient thermionic energy converters. Using low energy electron microscopy (LEEM) and in situ film growth, we show that substrate temperature control permits well-controlled fabrication of either epitaxial Cr[110] films or nanocrystalline Cr layers. We show that the work function of cesium saturated nanocrystalline Cr thin-films is ∼0.20 eV lower than that of epitaxial Cr[110] films. Our LEEM measurements of absorbed and reflected currents as a function of electron energy demonstrate that nanocrystallinity of cesiated chromium films results in 96% electron absorption in the range up to 1 eV above the work function, compared to just 79% absorption in cesiated crystalline Cr[110] films. These results point to metal films with suppressed crystallinity as an economical and scalable means to synthesize nanoengineered surfaces with optimized properties for next generation anode materials in high performance thermionic energy converters.
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