Some previous studies showed that the formation of several deep dark humus rich topsoils in Northern Europe was strongly influenced by the application of different organic materials by anthropogenic activities in former times. Such topsoils classified as plaggic Anthrosols also occurred in the Jaeren region in SW Norway. However, source material and formation time of these Plaggic Anthrosols have not yet been clarified. Close to this region we found further humus-rich topsoils in the Karmøy municipality (2 sites at main island of Karmøy and 1 site at Feøy). These soils show a thick humus-rich topsoil up to 30 cm, and their formation cannot only be explained by natural conditions. We analyzed the molecular signature of the soil organic matter (SOM) by benzene polycarboxylic acids (BPCA), non-targeted bulk SOM mass materials and the age of the SOM. The black carbon (BC) contents of the plaggic soils in Jaeren (mean 3.4 g kg-1) deliver clear evidence for inputs of combustion residues from ancient fire management and/or from settlements. The C XANES and Py-FIMS-spectra reveal relative enrichments of aromatic C and heterocyclic N compounds in the plaggic soils corresponding to the BC contents. In contrast, the humus-rich topsoils in Karmøy seem to be unaffected by fire management due to the low BC contents (mean 0.6 g kg-1) and the relative low portions of aromatic C and heterocyclic N compounds from C-XANES and Py-FIMS signature of the SOM ranged from 10.6 to 15.2 ‰ in the soils at the islands and 10.0 to 13.5 ‰ in Jaeren, corresponding to the Anthrosols in complementary archaeological literature implied that the soils in Jaeren and Karmøy have been formed between the Roman Iron Age (500 BC to AD 500) and the Viking Age (AD 800 to AD 1,000). Our results provide strong evidence for an anthropo-pedogenesis of the humus-rich topsoils in Karmøy and indicate parallels to the plaggic soils in Jaeren as well as to Anthrosols in the Baltic Sea region. Therefore, we propose to classify the humus-rich topsoils in Karmøy as Anthrosols. weed = 20 ‰). The AMS 14C dating and *Revision, Unmarked Click here to download Revision, Unmarked: Humus-rich topsoils in SW Norway_Revision, unmarked.doc Humus-rich topsoils in SW Norway-Molecular and isotopic signatures of soil organic matter as indicators for anthropo-pedogenesis
Regionally restricted, hums-rich topsoils in Southwest Norway and the Baltic Sea region of Germany and Denmark were formed by inputs of various amendments (combustion residues and marine biomass) and, therefore, were classified as Anthrosols. For a deeper insight into the ancient management practices, we investigated the elemental and P-composition in the upper and underlying horizons from 12 soil profiles in the Jæren region, at the islands of Karmøy and Feøy (Norway), at the island of Fehmarn and the peninsula of Wagrien (Germany), and at the islands of Poel (Germany) and Sjaelland (Denmark). We used aqua regia digestion and the complementary methods of sequential P fractionation, phosphorus K-edge X-ray absorption near edge structure (P-XANES) spectroscopy, and 31P nuclear magnetic resonance (31P-NMR) spectroscopy. Results were compared with the composition of differently amended and/or un-amended soils from other studies. In addition, archaeological literature was used to confirm possible inputs of specific P-containing amendments in ancient agriculture. The P composition from SF of the Anthrosols in Norway (44% NaOH-Pi >1 8% NaOH-Po > 14% NaHCO3-Pi, 12% H2SO4-P > 7% NaHCO3-Po > 3% residual-P = 3% resin-P) and complementary archaeological literature provided strong indication for the use of peat, sheep manure, compost, and human excreta. The Anthrosols in the Jæren region have been formed from peat, which had been used as alternative bedding material and had been mixed with sheep and/or cattle manure. The P-composition in the Anthrosols at the island of Fehmarn and at the peninsula of Wagrien (42% H2SO4-P > 25% residual-P > 10% NaOH-Po, 8% NaOH-Pi: > 6% NaHCO3-Pi and NaHCO3-Po, 4% resin-P) resulted from the application of domestic cattle manure. This was strongly supported by archaeological findings of cattle bones in this region, as well as high proportions of Ca-P, as confirmed by P-XANES. The predominance of Po in the Anthrosols at the island of Poel and Sjaelland (31% NaOH-Po > 23% NaHCO3-Po, 21% H2SO4-P > 11% NaOH-Pi > 8% NaHCO3-Pi > 4% residual-P, 3% resin-P, in agreement with results from 31P-NMR) indicated low ancient inputs of various excrement or manure. This was supported by low livestock history at the island of Poel. In conclusion, these agricultural techniques can be considered as sustainable P recycling and soil amendment since they improved soil fertility for many generations.
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