Temperature-dependent gas-phase 1H NMR
spectra of seven thiocarbonyl-substituted
N,N-dimethylthioamides
(YCSN(CH3)2) obtained at 300 MHz are
consistent with the following free activation energies
ΔG
⧧
298 (kcal
mol-1): Y = H, 22.5 (0.1);
CH3, 18.0 (0.1); F, 18.3 (0.1); Cl, 16.9 (0.2);
CF3, 17.2 (0.1); CH2CH3,
17.6
(0.1); CH(CH3)2, 16.3 (0.1). The
results are compared to condensed-phase values and to the
corresponding
gas-phase oxoamides.
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