In this work, we developed a fluorescence and photothermal microscope with extremely large scanning range and high spatial resolution. We demonstrated the capability of this instrument by simultaneously measuring the photoluminescence and photothermal signals of the CH3NH3PbI3 (MAPbI3) film. After scanning the MAPbI3 film on the scale of centimeters, we can obtain information of both emissive and nonemissive processes with a resolution of 200 nm at any location of the large area. We can clearly see the localized photothermal signal while the photoluminescence signal is uniform. These results directly prove that the emissive recombination happens all over the materials, but the nonemissive recombination happens only at certain localized quenching sites. The fluorescence and photothermal microscope with both large scanning range and high spatial resolution can provide information of all the relaxation channels of the excitons, showing potential applications for investigation of photophysical mechanisms in photoelectric materials.
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