Methacrylate-labeled SBA-15 has been successfully synthesized from calcined SBA-15 and commercially available 3-trichlorosilyl propylmethacrylate. This material undergoes efficient thiol–ene “click reaction” with a variety of both thiol and disulfide-containing substrates in aqueous and organic media. The products were thoroughly characterized by a variety of analytical techniques including multinuclear (13C, 29Si) solid-state NMR, TG-DTA, and nitrogen adsorption desorption studies. Disulfide-containing substrates in which the TCEP-mediated reduction of the disulfide bond and its subsequent addition to the methacrylate group anchored in SBA-15 in one-pot were used to synthesize a silica–protein hybrid material composed of biotin-labeled SBA-15 and streptavidin. Electrochemically active material was synthesized from the reaction of ferrocene-containing thiol and the methacrylate-labeled SBA-15. The ease of synthesis for the methacrylate-labeled SBA-15 material together with its ability to undergo efficient chemoselective thiol–ene reaction would make it a very attractive platform for the development of covalently anchored enzymes and sensors.
Assembly of nanoparticles into free-standing threedimensional networks has implications for a wide range of applications. We show that dynamic templating of surfactant hexagonal domains is a facile technique to organize nanoparticles into a network of particulate strands. Dispersed particles (>10 nm), independent of particle chemistry, assemble into networks, when the surfactant matrix cools into the hexagonal phase. We demonstrate assembly of inorganic, polymeric, and protein nanoparticles into networks. Where particle assembly is reversible, particles are coated with polymers that are subsequently cross-linked to stabilize the networks after surfactant removal. This technique involves near ambient temperatures and a benign water wash for template removal. The network mesh size can be varied from submicrometers to tens of micrometers by controlling the cooling rate. Particle networks can be flow-oriented prior to cross-linking, and interpenetrating networks can also be formed.
Metal–semiconductor hybrids
are a promising architecture
for functional nanostructures because they efficiently promote charge
separation. The morphology of the hybrid supports two mechanisms of
charge generation and transfer, namely, the excitation of electrons
to the conduction band of the semiconductor or the induction of surface
plasmon resonance on the metal. Here, we compared the photocatalytic
activity of nanoparticles with a core–shell or dimer morphology,
using Pt, Pd, or Au as the metal and Cu2ZnSnS4 (CZTS), which comprises abundant and environmentally friendly elements,
as the semiconductor. Their performance as photocatalysts was evaluated
by using Methylene Blue (MB) degradation under light irradiation.
We found that although large Au cores improved the photocatalytic
activity of the CZTS nanoparticles, the highest catalytic activity
was that of Pt–CZTS and Pd–CZTS dimers. Conversely,
using small metal particles as cores degraded the activity of the
CZTS due to the formation of an internal boundary and the occupation
of potentially optically active volume. In addition, the results point
out that depositing multiple metal particles is not beneficial for
photocatalysis.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.