Materials that exhibit ferromagnetism, interfacial stability, and tunability are highly desired for the realization of emerging magnetoelectronic phenomena in heterostructures. Here we present the GdAg2 monolayer alloy, which possesses all such qualities. By combining X-ray absorption, Kerr effect, and angle-resolved photoemission with ab initio calculations, we have investigated the ferromagnetic nature of this class of Gd-based alloys. The Curie temperature can increase from 19 K in GdAu2 to a remarkably high 85 K in GdAg2. We find that the exchange coupling between Gd atoms is barely affected by their full coordination with noble metal atoms, and instead, magnetic coupling is effectively mediated by noble metal-Gd hybrid s,p-d bands. The direct comparison between isostructural GdAu2 and GdAg2 monolayers explains how the higher degree of surface confinement and electron occupation of such hybrid s,p-d bands promote the high Curie temperature in the latter. Finally, the chemical composition and structural robustness of the GdAg2 alloy has been demonstrated by interfacing them with organic semiconductors or magnetic nanodots. These results encourage systematic investigations of rare-earth/noble metal surface alloys and interfaces, in order to exploit them in magnetoelectronic applications.
Understanding how specific atom sites on metal surfaces lower the energy barrier for chemical reactions is vital in catalysis. Studies on simplified model systems have shown that atoms arranged as steps on the surface play an important role in catalytic reactions, but a direct comparison of how the light-off temperature is affected by the atom orientation on the step has not yet been possible due to methodological constraints. Here we report in situ spatially resolved measurements of the CO2 production over a cylindrical-shaped Pd catalyst and show that the light-off temperature at different parts of the crystal depends on the step orientation of the two types of steps (named A and B). Our finding is supported by density functional theory calculations, revealing that the steps, in contrast to what has been previously reported in the literature, are not directly involved in the reaction onset but have the role of releasing stress.
Controlling anisotropy and exchange coupling in patterned magnetic nanostructures is the key for developing advanced magnetic storage and spintronic devices. We report on the antiferromagnetic interaction between a Co nanodot array and its supporting GdAu2 nanotemplate that induces large anisotropy values in individual Co nanodots. In clear contrast with nonmagnetic Au substrates, GdAu2 triggers an earlier switch from out-of-plane anisotropy in monatomic high dots to in-plane when the dot height becomes biatomic.
Reduced hot cracking susceptibility is essential to ensure the flawless manufacturing of nickel superalloys typically employed in welded aircraft engine structures. The hot cracking of precipitation strengthened alloy 718 mainly depends on chemical composition and microstructure resulting from the thermal story. Alloy 718 is usually welded in a solution annealed state. However, even with this thermal treatment, cracks can be induced during standard industrial manufacturing conditions, leading to costly and time-consuming reworking. In this work, the cracking susceptibility of wrought and investment casting alloy 718 is studied by the Varestraint test. The test is performed while applying different welding conditions, i.e., continuous tungsten inert gas (TIG), low frequency pulsed TIG, continuous laser beam welding (LBW) and pulsed LBW. Welding parameters are selected for each welding technology in order to meet the welding quality criteria requested for targeted aeronautical applications, that is, full penetration, minimum cross-sectional welding width and reduced overhang and underfill. Results show that the hot cracking susceptibility of LBW samples determined by the Varestraint test is enhanced due to extended center line hot cracking, resulting in a fish-bone like cracking pattern. On the contrary, the minor effect of material source (wrought or casting), grain size and pulsation is observed. In fact, casting samples with a 30 times coarser grain size have shown better performance than wrought material.
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