The aim of this study was to assess the effect of endodontic chemical substances on the retention of fiber posts luted using a self-adhesive cement. Single-canal human roots of 75 teeth were divided into 5 groups (n = 15). Root canals were instrumented with one of the following substances: 0.9% NaCl (control); 5.25% sodium hypochlorite; 5.25% Sodium hypochlorite + 17% EDTA; 2% chlorhexidine gel; 2% chlorhexidine gel + 17% EDTA. After chemo-mechanical preparation, fiber post cementation was performed with self-adhesive resin cement (RelyX Unicem, 3 M/ESPE). One-way ANOVA was performed followed by a multiple comparison Tukey post hoc test (α = 5%). The use of 2% chlorhexidine gel resulted bond strength statistically similar to the control group (p = 0.418), which was higher than the other groups. A final irrigation with 17% EDTA significantly reduced bond strength (p < 0.001). The use of 5.25% sodium hypochlorite negatively affected the bond strength, either with or without a final irrigation with 17% EDTA (p < 0.001). Our results suggest that 2% chlorhexidine gel used during endodontic chemo-mechanical preparation, without a final irrigation with 17% EDTA, promotes a more favorable condition to the retention of fiber posts luted using a self-adhesive cement than 5.25% sodium hypochlorite.
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