The effect of filler surface functionalization with 3-aminopropyltriethoxysilane (APTES) on the charge trapping and transport was studied in polypropylene (PP)/(ethylene-octene) copolymer (EOC)/silica nanodielectrics. Different reaction conditions were utilized for silica functionalization to alter the deposited layer morphology. This approach made it possible to engineer the filler−polymer interface to achieve optimized dielectric properties for the nanocomposites. The successful chemical modification of the silica surface was confirmed via thermogravimetric analysis (TGA), Fourier-transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). Subsequently, the effect of the engineered filler−polymer interface on the nanocomposites' crystallinity was analyzed with differential scanning calorimetry (DSC). Scanning electron microscopy (SEM) was utilized to observe the morphology of the nanocomposite as well as the silica dispersion. Finally, the effect of the silica functionalization on the dielectric properties of PP/EOC/silica nanocomposites was tested via thermally stimulated depolarization current (TSDC) and broadband dielectric spectroscopy (BDS). The results suggested that the presence of the amine functionality on the silica reduces interfacial losses in nanocomposites, and hinders further injection of space charge by introducing deep trap states at the filler−polymer interface. Under certain conditions, APTES can form an "island-like" morphology on the silica surface. These islands can facilitate nucleation, inducing transcrystallization at the filler−polymer interface. The island-like structures present on the silica would further contribute to the induction of deep traps at the filler−polymer interface resulting in the reduction of space charge injection.
The present study discusses that filler–filler mechanical engagement resulting from the grafted long-chain silanes on the silica surface is indeed a reinforcing mechanism in rubber composites, as already speculated by nonlinear viscoelastic properties in our previous study. The existence and severity of such a phenomenon are assessed purely by isolating the energetic contribution of reinforcement from interfering with filler mechanical engagement in the silica network formation and breakdown processes. In a novel approach, the driving force of fillers to flocculate energetically at elevated temperatures was defined using surface energy theories, and it was adjusted to be similar in two composites having silica treated by short- and long-chain silanes. Filler–filler mechanical engagement was monitored by tracking network formation (filler flocculation) in a matrix of styrene–butadiene rubber and also by conducting various dynamic viscoelastic experiments on liquid paraffin suspensions having short- and long-chain silica of similar surface energy. Results consistently confirmed the existence of mechanical engagement between silica particles having the long-chain silane in both rubber compounds and paraffin suspensions. The results may find applications in the rolling resistance of tires, for example, where stabilization of the filler network by displacing the peak energy dissipation of the network breakdown from applied service strains to larger values would be of technical importance.
Novel nanocomposites for dielectric applications-based polypropylene/poly(ethylene-co-octene) (PP/POE) blends filled with nano silica are developed in the framework of the European ‘GRIDABLE’ project. A tailor-made low-pressure-plasma reactor was applied in this study for an organic surface modification of silica. Acetylene gas was used as the monomer for plasma polymerization in order to deposit a hydrocarbon layer onto the silica surface. The aim of this modification is to increase the compatibility between silica and the PP/POE blends matrix in order to improve the dispersion of the filler in the polymer matrix and to suppress the space charge accumulation by altering the charge trapping properties of these silica/PP/POE blends composites. The conditions for the deposition of the acetylene plasma-polymer onto the silica surface were optimized by analyzing the modification in terms of weight loss by thermogravimetry (TGA). X-ray photoelectron spectroscopy (XPS) and energy-dispersive X-ray fluorescence spectroscopy (EDX) measurements confirmed the presence of hydrocarbon compounds on the silica surface after plasma modification. The acetylene plasma modified silica with the highest deposition level was selected to be incorporated into the PP/POE blends matrix. X-ray diffraction (XRD) showed that there is no new crystal phase formation in the PP/POE blends nanocomposites after addition of the acetylene plasma modified silica. Differential scanning calorimetry results (DSC) show two melting peaks and two crystallization peaks of the PP/POE blends nanocomposites corresponding to the PP and POE domains. The improved dispersion of the silica after acetylene plasma modification in the PP/POE blends matrix was shown by means of SEM–EDX mapping. Thermally stimulated depolarization current (TSDC) measurements confirm that addition of the acetylene plasma modified silica affects the charge trapping density and decreases the amount of injected charges into PP/POE blends nanocomposites. This work shows that acetylene plasma modification of the silica surface is a promising route to tune charge trapping properties of PP/POE blend-based nanocomposites.
This paper focuses on novel insulation polypropylene/poly(ethylene-co-octene) (PP/POE) nanocomposites for High Voltage Direct Current (HVDC) cable application. The composites contain silica modified by a solvent-free method using silanes differing in polarity and functional moieties. Thermogravimetric Analysis and Fourier Transform Infrared Spectroscopy showed that the solvent-free method is an effective way to modify silica by silanes. Silica/PP/POE nanocomposites were prepared in a mini twin-screw compounder, and the effect of silica on crystallization, dispersibility and dielectric properties of the samples was investigated. Differential Scanning Calorimetry results showed that the unmodified and modified silicas acted as nucleation agents and increased the onset of the crystallization temperature of the polymeric matrix. Scanning Electron Microscopy images showed that the silica is mostly located in the PP phase matrix. For the PP/POE nanocomposites filled with unpolar silica, a higher trap density (measured by Thermally Stimulated Depolarization Current, TSDC) was found; this might be caused by the larger interfacial area due to a better dispersion of the unpolar silica in the polymeric matrix. Polar silicas introduce deeper traps than the unpolar ones, which is most likely due to the hetero-atom introduction. Nitrogen atoms were found to have the strongest effect on the charge trapping properties. According to these results, amine-modified silica is a promising candidate for PP/POE nanocomposites for HVDC cable applications.
We evaluated the significance of mechanical engagement and energetic interaction between a polymer and a filler as two reinforcing mechanisms in SBR composites containing silica modified by short- and long-chain silanes. To exclude mechanical contributions of reinforcement from that of energetic contributions, surface energy of silica particles was systematically adjusted to prepare fillers of identical and diverse surface energies. Having analyzed interactions using a temperature sweep in a small-strain oscillatory test and a uniaxial tension test, results indicated that the chain length of the silane has remarkable influence on energetic filler–filler and filler–polymer interactions, but no detectable difference associated with filler–polymer mechanical engagement was observed from these experiments. However, dynamic strain sweep experiments showed that the rate of breakage of the filler network (Payne effect) is less for the composite having long-chain silane compared to that having short-chain silane. It was hypothesized that this behavior could be correlated to mechanical engagements of long-chain silanes existing on the filler structure.
Novel nanocomposites for dielectric applications based on a polypropylene (PP) blend filled with nanosilica are developed in the frame of the European 'GRIDABLE' project. A systematic study of the influence of surface modification of the nanosilica on the dielectric properties of the PP/silica blend was performed. The main goal of this investigation was to modify the chemical composition of the silica surface, which is expected to improve the charge trapping properties of the nanocomposites. For the modification of the silica surface, a "green" approach was utilized: a dry silanization method, which is performed without the need of a solvent. Eight different silanes were investigated in this study, which are categorized into three different groups: I) Aliphatic silanes with a different number of alkoxy groups II) Hydrocarbon silanes containing delocalized electron clouds III) Polar silanes containing hetero elements (nitrogen, sulfur or oxygen) The results of the thermogravimetric analysis (TGA) show higher weight loss of the modified silicas in comparison to the unmodified one. This indicates that the dry process is an effective method to perform silica surface modification using alkoxysilanes. The charge trapping properties were studied by Thermally Stimulated Depolarization Current (TSDC) measurements. The obtained TSDC results show that the trap density peak is not significantly shifted in temperature when the silica is modified with functional groups elementally similar to the polymer matrix. However, their incorporation influences the traps density and suppress the deeper traps occurring near the range of the melting temperature of PP. When the silica surface is modified with a precursor containing a hetero element, it has an effect on both, trap level depth as well as density. Depending on the type of the hetero element (sulfur, nitrogen, oxygen), the trap depth shifted to higher temperatures, and the trap density decreased to significantly lower levels. Nitrogen appears to have the strongest effect on the charge trap properties. All these first stage of results show that incorporation of modified nanosilica into a PP matrix seems to be a promising approach to tailor its electric properties. Further development of these composites would lead to benefits for high-voltage cable and capacitors applications.
This paper presents space charge accumulation characteristics of cable grade and capacitor grade nanostructured polypropylene (PP) materials, providing initial results regarding the electrical properties of nanofilled PP materials belonging to the European project GRIDABLE. This project has the aim to develop DC cable extruded insulation and MV and LV DC capacitor films having enhanced performance with respect to presently used materials. The paper shows that nanostructuration may be beneficial, especially at higher temperature, to improve the capacitor-grade material performance. On the other hand, this work validates the importance of surface functionalization of nanofillers, leading to lower space charge accumulation on DC cable-grade materials.
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