Although offshore freshened groundwater (OFG) systems have been documented in numerous continental margins worldwide, their geometry, controls and emplacement dynamics remain poorly constrained. Here we integrate controlled-source electromagnetic, seismic reflection and borehole data with hydrological modelling to quantitatively characterise a previously unknown OFG system near Canterbury, New Zealand. The OFG system consists of one main, and two smaller, low salinity groundwater bodies. The main body extends up to 60 km from the coast and a seawater depth of 110 m. We attribute along-shelf variability in salinity to permeability heterogeneity due to permeable conduits and normal faults, and to recharge from rivers during sea level lowstands. A meteoric origin of the OFG and active groundwater migration from onshore are inferred. However, modelling results suggest that the majority of the OFG was emplaced via topographically-driven flow during sea level lowstands in the last 300 ka. Global volumetric estimates of OFG will be significantly revised if active margins, with steep coastal topographies like the Canterbury margin, are considered.

First reported in the 1960s, offshore freshened groundwater (OFG) has now been documented in most continental margins around the world. In this review we compile a database documenting OFG occurrences and analyze it to establish the general characteristics and controlling factors. We also assess methods used to map and characterize OFG, identify major knowledge gaps, and propose strategies to address them. OFG has a global volume of 1 × 10 6 km 3 ; it predominantly occurs within 55 km of the coast and down to a water depth of 100 m. OFG is mainly hosted within siliciclastic aquifers on passive margins and recharged by meteoric water during Pleistocene sea level lowstands. Key factors influencing OFG distribution are topography-driven flow, salinization via haline convection, permeability contrasts, and the continuity/connectivity of permeable and confining strata. Geochemical and stable isotope measurements of pore waters from boreholes have provided insights into OFG emplacement mechanisms, while recent advances in seismic reflection profiling, electromagnetic surveying, and numerical models have improved our understanding of OFG geometry and controls. Key knowledge gaps, such as the extent and function of OFG, and the timing of their emplacement, can be addressed by the application of isotopic age tracers, joint inversion of electromagnetic and seismic reflection data, and development of three-dimensional hydrological models. We show that such advances, combined with site-specific modeling, are necessary to assess the potential use of OFG as an unconventional source of water and its role in sub-seafloor geomicrobiology. Plain Language Summary This review paper considers offshore freshened groundwater (OFG), which is water hosted in sediments and rocks below the seafloor, with a total dissolved solid concentration lower than seawater. We have compiled >300 records to demonstrate that freshened groundwater occurs offshore on most continents around the world and has a global volume of 1 × 10 6 km 3. The majority of OFG was deposited when sea level was lower than today and is hosted in sandy sub-seafloor layers that are located within 55 km of coasts in water depths less than 100 m. We present a range of geochemical, geophysical, and modeling approaches that have successfully been used to investigate OFG systems. We also propose approaches to address key scientific questions related to OFG, including whether it may be used as an unconventional source of potable water in coastal areas.

Seafloor massive sulphides (SMSs) are regarded as a potential future resource to satisfy the growing global demand of metals including copper, zinc and gold. Aside from mining and retrieving profitable amounts of massive sulphides from the seafloor, the present challenge is to detect and delineate significant SMS accumulations, which are generally located near mid-ocean ridges and along submarine volcanic arc and backarc spreading centres. Currently, several geophysical technologies are being developed to detect and quantify SMS occurrences that often exhibit measurable contrasts in their physical parameters compared to the surrounding host rock. Here, we use a short, fixed-offset controlled source electromagnetic (CSEM) system and a coincident-loop transient electromagnetic (TEM) system, which in theory allow the detection of SMS in the shallow seafloor due to a significant electrical conductivity contrast to their surroundings. In 2016, CSEM and TEM experiments were carried out at several locations near the TransAtlantic Geotraverse hydrothermal field to investigate shallow occurrences of massive sulphides below the seafloor. Measurements were conducted in an area that contains distinct SMS sites located several kilometres off-axis from the Mid-Atlantic ridge, some of which are still connected to hydrothermal activity and others where hydrothermal activity has ceased. Based on the quality of the acquired data, both experiments were operationally successful. However, the data analysis indicates bias caused by three-dimensional (3D) effects of the rough bathymetry in the study area and, thus, data interpretation remains challenging. Therefore, we study the influence of 3D bathymetry for marine CSEM and TEM experiments, focusing on shallow 3D conductors located beneath mound-like structures. We analyse synthetic inversion models for attributes associated with 3D distortions of CSEM and TEM data that are not sufficiently accounted for in conventional 1D (TEM) and 2D (CSEM) interpretation schemes. Before an adequate quantification of SMS in the region is feasible, these 3D effects need to be studied to avoid over/underestimation of SMS using the acquired EM data. The sensitivity of CSEM and TEM to bathymetry is investigated by means of 3D forward modelling, followed by 1D (TEM) and 2D (CSEM) inversion of the synthetic data using realistic error conditions. Subsequently, inversion models of the synthetic 3D data are analysed and compared to models derived from the measured data to illustrate that 3D distortions are evident in the recorded data sets.

Carbonate lithologies host considerable quantities of the Earth's freshwater resources and partially supply a quarter of the global population with drinkable water. Carbonates constitute substantial amounts of the global coastlines, yet it is not known if and how they can sustain freshened groundwater offshore. Here, we use controlled source electromagnetic, seismic reflection, and core sample data to derive a lithological model for the eastern margin of the Maltese Islands and identify four distinct resistivity anomalies within the Upper Coralline Limestone, Globigerina Limestone, and Blue Clay formations. The anomalies hosted in the former are likely associated to low porosities, whereas the anomaly within the latter is indicative of pore fluid freshening. Hydrogeological modeling suggests that freshened pore fluids, emplaced during sea-level lowstands and preserved in low permeability units, are potentially still found within carbonate shelves. However, resource potential is low due to its relict nature and low permeability host environment.

The marine differential electric dipole (DED) is applied for the first time to study a subseafloor groundwater body in the coastal region of Bat Yam, Israel. Previous marine long-offset transient electromagnetic applications detected this freshwater body underneath the Mediterranean seafloor. We have applied the novel DED method for the first time in the marine environment to further investigate this natural phenomenon. The main objectives are to locate the freshwater-seawater interface at the western aquifer edge and to identify the mechanism controlling this freshwater occurrence beneath the seafloor. The acquired step-on signals allow one to detect the freshwater body in the vicinity of the Israeli coastline at a depth of approximately 70 m beneath the seafloor. However, aquifer thickness is only poorly determined and may vary between 40 and 100 m. A lateral resistivity contrast is observable between adjacent 1D inversion models and also apparent in data profile curves that constrain the seaward extent of the detected resistive body to a distance of less than 4 km from the coastline. A subsequent 2.5D forward-modeling study aims to find a subseafloor resistivity distribution that adequately explains all measured DED data simultaneously. The results further constrain the lateral extent of the resistive aquifer to approximately 3.6–3.7 km from the Israeli coast. Furthermore, the data indicate that the aquifer system may be susceptible to seawater intrusion, as a superior data fit is achieved if a brackish water zone of approximately [Formula: see text] with a lateral extent of less than 300 m is located at the head of the freshwater body.

We present high-resolution resistivity imaging of gas hydrate pipe-like structures, as derived from marine controlled-source electromagnetic (CSEM) inversions that combine towed and ocean-bottom electric field receiver data, acquired from the Nyegga region, offshore Norway. Two-dimensional CSEM inversions applied to the towed receiver data detected four new prominent vertical resistive features that are likely gas hydrate structures, located in proximity to a major gas hydrate pipe-like structure, known as the CNE03 pockmark. The resistivity model resulting from the CSEM data inversion resolved the CNE03 hydrate structure in high resolution, as inferred by comparison to seismically constrained inversions. Our results indicate that shallow gas hydrate vertical features can be delineated effectively by inverting both ocean-bottom and towed receiver CSEM data simultaneously. The approach applied here can be utilised to map and monitor seafloor mineralisation, freshwater reservoirs, CO 2 sequestration sites and near-surface geothermal systems.

The Eastern Mediterranean has been used as a passageway for human migration from Africa to the Middle East, the Balkans and Europe. The Azraq basin in the eastern desert of Jordan has been a major spot for human settlements since the middle Pleistocene. The former lake in the basin centre has developed to a hyper‐saline alluvial mudflat, the Qa’ Al Azraq. In the mudflat thick sequences of alluvial sediments are deposited. Such sediment successions are promising archives used for reconstructing a paleoclimate. In order to identify geological structures and to derive suitable borehole locations in the area for a paleoclimatical reconstruction, the Transient Electromagnetic (TEM) and the Electrical Resistivity Tomography (ERT) methods were utilized. Two transects were investigated from the edge of the basin to the basin centre, crossing three geological formations. The data sets of both methods are interpreted by 1D and 2D inversion algorithms and appraised by inversion statistics. Previously uncertain geological boundaries are determined from geoelectrical models along both transects. Furthermore, a transition zone from fresh to saline groundwater is clearly detected.

 Seafloor massive sulfide deposits can be modelled in 3D by inverting seafloor magnetic and gravity data. Sparse drilling can be improved upon with geophysical inverse modelling to enhance 3D deposit models. An updated massive sulfide tonnage estimate was determined for the Trans-Atlantic Geotraverse active mound.