It has been argued that charged Anti-de Sitter (AdS) black holes have similar thermodynamic behavior as the Van der Waals fluid system, provided one treats the cosmological constant as a thermodynamic variable (pressure) in an extended phase space. In this paper, we disclose the deep connection between charged AdS black holes and Van der Waals fluid system without extending the phase space. We keep the cosmological constant as a fixed parameter and instead, treat the square of the charge of black hole, Q 2 , as a thermodynamic variable. Therefore, we write the equation of state as Q 2 = Q 2 (T, Ψ) where Ψ (conjugate of Q 2 ) is the inverse of the specific volume, Ψ = 1/v. This allows us to complete the analogy of charged AdS black holes with Van der Waals fluid system and derive the phase transition as well as critical exponents of the system. We identify a thermodynamic instability in this new picture with real analogy to Van der Waals fluid with physically relevant Maxwell construction. We therefore study the critical behavior of isotherms in Q 2 − Ψ diagram and deduce all the critical exponents of the system and determine that the system exhibits a small-large black hole phase transition at the critical point (Tc, Q 2 c , Ψc). This alternative view is important as one can imagine such a change for a given single black hole i. e. acquiring charge which induces the phase transition. Finally, we disclose the microscopic properties of charged AdS black holes by using thermodynamic geometry. Interestingly, we find that scalar curvature has a gap between small and large black holes, and this gap becomes exceedingly large as one moves away from the critical point along the transition line. Therefore, we are able to attribute the sudden enlargement of the black hole to the strong repulsive nature of the internal constituents at the phase transition.

We disclose a novel phase transition in black hole physics by investigating thermodynamics of charged dilaton black holes in an extended phase space where the charge of the black hole is regarded as a fixed quantity. Along with the usual critical (second-order) as well as the first-order phase transitions in charged black holes, we find that a finite jump in Gibbs free energy is generated by dilaton-electromagnetic coupling constant, α, for a certain range of pressure. This novel behavior indicates a small/large black hole zeroth-order phase transition in which the response functions of black holes thermodynamics diverge e.g. isothermal compressibility. Such zeroth-order transition separates the usual critical point and the standard first-order transition curve. We show that increasing the dilaton parameter(α) increases the zeroth-order portion of the transition curve. Additionally, we find that the second-order (critical) phase transition exponents are unaffected by the dilaton parameter, however, the condition of positive critical temperature puts an upper bound on the dilaton parameter (α < 1).

We investigate thermodynamic phase structure and critical behaviour of Born-Infeld (BI) black holes in an anti-de Sitter (AdS) space, where the charge of the system can vary and the cosmological constant (pressure) is fixed. We find that the BI parameter crucially affects the temperature of the black hole when the horizon radius, r+, is small. We observe that depending on the value of the nonlinear parameter, β, BI-AdS black hole may be identified as RN black hole for Q ≥ Qm, and Schwarzschild-like black hole for Q < Qm, where Qm = 1/ (8πβ) is the marginal charge. We analytically calculate the critical point (Qc, Tc, r+c) by solving the cubic equation and study the critical behaviour of the system. We also explore the behavior of Gibbs free energy for BI-AdS black hole. We find out that the phase behaviour of BI-AdS black hole depends on the charge Q. For Q > Qc, the Gibbs free energy is single valued and the system is locally stable (CQ > 0), while for Q < Qc, it becomes multivalued and CQ < 0. In the range of Qz < Q < Qc, a first order phase transition occurs between small black hole (SBH) and large black hole (LBH). Interestingly enough, in the range of Qt ≤ Q ≤ Qz, a reentrant phase transition occurs between intermediate (large) black hole, SBH and LBH in Schwarzschild-type region. This means that in addition to the first order phase transition which separates SBH and LBH, a finite jump in Gibbs free energy leads to a zeroth order phase transition between SBH and intermediate black hole (LBH) where initiates from Q = Qz and terminates at Q = Qt.

Understanding the microscopic behavior of the black hole ingredients has been one of the important challenges in black hole physics during the past decades. In order to shed some light on the microscopic structure of black holes, in this paper, we explore a recently observed phenomenon for black holes namely reentrant phase transition, by employing the Ruppeiner geometry. Interestingly enough, we observe two properties for the phase behavior of small black holes that leads to reentrant phase transition. They are correlated and they are of the interaction type. For the range of pressure in which the system underlies reentrant phase transition, it transits from the large black holes phase to the small one which possesses higher correlation than the other ranges of pressures. On the other hand, the type of interaction between small black holes near the large/small transition line differs for usual and reentrant phase transitions. Indeed, for the usual case, the dominant interaction is repulsive whereas for the reentrant case we encounter an attractive interaction. We show that in the reentrant phase transition case, the small black holes behave like a bosonic gas whereas in the usual phase transition case, they behave like a quantum anyon gas.

We investigate analytically as well as numerically the properties of s-wave holographic superconductors in d-dimensional spacetime and in the presence of Logarithmic nonlinear electrodynamics. We study three aspects of this kind of superconductors. First, we obtain, by employing analytical Sturm-Liouville method as well as numerical shooting method, the relation between critical temperature and charge density, ρ, and disclose the effects of both nonlinear parameter b and the dimensions of spacetime, d, on the critical temperature T c . We find that in each dimension, T c /ρ 1/(d−2) decreases with increasing the nonlinear parameter b while it increases with increasing the dimension of spacetime for a fixed value of b. Then, we calculate the condensation value and critical exponent of the system analytically and numerically and observe that in each dimension, the dimensionless condensation get larger with increasing the nonlinear parameter b. Besides, for a fixed value of b, it increases with increasing the spacetime dimension. We confirm that the results obtained from our analytical method are in agreement with the results obtained from numerical shooting method. This fact further supports the correctness of our analytical method. Finally, we explore the holographic conductivity of this system and find out that the superconducting gap increases with increasing either the nonlinear parameter or the spacetime dimension. * asheykhi@shirazu.ac.ir