Photocatalysis based technologies have a key role in addressing important challenges of the ecological transition, such as environment remediation and conversion of renewable energies. Photocatalysts can in fact be used in hydrogen (H2) production (e.g., via water splitting or photo-reforming of organic substrates), CO2 reduction, pollution mitigation and water or air remediation via oxidation (photodegradation) of pollutants. Titanium dioxide (TiO2) is a “benchmark” photocatalyst, thanks to many favorable characteristics. We here review the basic knowledge on the charge carrier processes that define the optical and photophysical properties of intrinsic TiO2. We describe the main characteristics and advantages of TiO2 as photocatalyst, followed by a summary of historical facts about its application. Next, the dynamics of photogenerated electrons and holes is reviewed, including energy levels and trapping states, charge separation and charge recombination. A section on optical absorption and optical properties follows, including a discussion on TiO2 photoluminescence and on the effect of molecular oxygen (O2) on radiative recombination. We next summarize the elementary photocatalytic processes in aqueous solution, including the photogeneration of reactive oxygen species (ROS) and the hydrogen evolution reaction. We pinpoint the TiO2 limitations and possible ways to overcome them by discussing some of the “hottest” research trends toward solar hydrogen production, which are classified in two categories: (1) approaches based on the use of engineered TiO2 without any cocatalysts. Discussed topics are highly-reduced “black TiO2”, grey and colored TiO2, surface-engineered anatase nanocrystals; (2) strategies based on heterojunction photocatalysts, where TiO2 is electronically coupled with a different material acting as cocatalyst or as sensitizer. Examples discussed include TiO2 composites or heterostructures with metals (e.g., Pt-TiO2, Au-TiO2), with other metal oxides (e.g., Cu2O, NiO, etc.), direct Z-scheme heterojunctions with g-C3N4 (graphitic carbon nitride) and dye-sensitized TiO2.
A review of recent advances in flexible printed gas sensors is presented. During the last years, flexible electronics has started to offer new opportunities in terms of sensors features and their possible application fields. The advent of this technology has made sensors low-cost, thin, with a large sensing area, lightweight, wearable, flexible, and transparent. Such new characteristics have led to the development of new gas sensor devices. The paper makes some statistical remarks about the research and market of the sensors and makes a shot of the printing technologies, the flexible organic substrates, the functional materials, and the target gases related to the specific application areas. The conclusion is a short notice on perspectives in the field.
The passage of an ultrasonic wave through a mixture of polyborosiloxane and silicon carbide abrasive, when used in a honing process, causes heating due to the attenuation of the said wave. This is critical to the honing process since the temperature in the components being treated must be limited to about 70 "C. A numerical model of the heat generation and transfer processes in the polishing medium is being formulated, which requires knowledge of the thermophysical properties of the mixture. This investigation concentrates on the experimental determination of thermal conductivity, specific heat capacity and surface heat transfer coefficient for various mixtures of polyborosiloxane and silicon carbide abrasive. Theoretical, semi-empirical and empirical models are derived for the variation of these thermal properties as functions of both material composition and temperature.
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