a b s t r a c tShort term electricity trading to balance generation and demand provides an economic opportunity to integrate larger shares of variable renewable energy sources in the power grid. Recently, many regulatory market environments are reorganized to allow short term electricity trading. This study seeks to quantify the benefits of solar forecasting for energy imbalance markets (EIM). State-of-the-art solar forecasts, covering forecast horizons ranging from 24 h to 5 min are proposed and compared against the currently used benchmark models, persistence (P) and smart persistence (SP). The implemented reforecast of numerical weather prediction time series achieves a skill of 14.5% over the smart persistence model. Using the proposed forecasts for a forecast horizon of up to 75 min for a single 1 MW power plant reduces required flexibility reserves by 21% and 16.14%, depending on the allowed trading intervals (5 and 15 min). The probability of an imbalance, caused through wrong market bids from PV solar plants, can be reduced by 19.65% and 15.12% (for 5 and 15 min trading intervals). All EIM stakeholders benefit from accurate forecasting. Previous estimates on the benefits of EIMs, based on persistence model are conservative. It is shown that the design variables regulating the market time lines, the bidding and the binding schedules, drive the benefits of forecasting.

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The surfactant-like peptide (Ala)-(Asp) (AD) is shown to self-assemble into ultrathin (3 nm thick) nanosheets in aqueous solution above a critical aggregation concentration. A combination of circular dichroism and FTIR spectroscopy and X-ray diffraction shows that the nanosheets comprise interdigitated bilayers of the peptide with β-sheet conformation. The self-assembly can be modulated by addition of hexamethylenediamine which is expected to interact with the anionic C terminus (and C-terminal D residue) of the peptide. Multiple ordered nanostructures can be accessed depending on the amount of added diamine. Nanosheet and bicontinuous network structures were observed using cryogenic-TEM and small-angle X-ray scattering. Addition of hexamethylenediamine at a sufficiently large molar ratio leads to disruption of the ordered nanostructure and the formation of a solution of AD-diamine molecular complexes with highly charged end groups. The multiple acid-functionalized nanostructures that are accessible in this system are expected to have many applications in the fabrication of new nanomaterials.