Obtaining absolute temperatures of the ocean in deep time is complicated by the lack of constraints on seawater chemistry. Seawater salinity, carbonate ion concentration, δ18O, and elemental abundance changes may obscure widely applied paleoproxies. In addition, with foraminifera‐based proxies applied over long time scales or through major transitions, taxonomic turnover can impair the robustness of a record. While requiring larger sample sizes than most other proxies, the clumped isotope method is independent of seawater chemistry. Here we test if small benthic foraminifera precipitate their carbonate in equilibrium with respect to the clumped isotope thermometer and if there are any species‐specific vital effects. We find that benthic foraminifera fall on the same calibration line as the majority of carbonate minerals including inorganic calcite. In addition, we find no offsets that can be attributed to a species‐specific for any of the samples. This finding implies that a necessary amount of sample material can be obtained by aggregating over multiple taxa of benthic foraminifera and allows for the application of this proxy over major climatic transitions that coincide with seawater chemistry changes and foraminifera extinctions.
Abstract. While there are no indications of mixing back to 800 000 years in the EPICA Dome C ice core record, comparison with marine sediment records shows significant differences in the timing and duration of events prior to stage 11 (∼430 ka, thousands of years before 1950). A relationship between the isotopic composition of atmospheric oxygen (δ 18 O of O 2 , noted δ 18 O atm ) and daily northern hemisphere summer insolation has been observed for the youngest four climate cycles. Here we use this relationship with new δ 18 O of O 2 measurements to show that anomalous flow in the bottom 500 m of the core distorts the duration of events by up to a factor of 2. By tuning δ 18 O atm to orbital precession we derive a corrected thinning function and present a revised age scale for the interval corresponding to Marine Isotope Stages 11-20 in the EPICA Dome C ice core. Uncertainty in the phasing of δ 18 O atm with respect to insolation variations in the precession band limits the accuracy of this new agescale to ±6 kyr (thousand of years). The previously reported ∼30 kyr duration of interglacial stage 11 is unchanged. In contrast, the duration of stage 15.1 is reduced by a factor of 2, from 31 to 16 kyr.
It has been proposed that the rapid rise of atmospheric CO 2 across the last deglaciation was driven by the release of carbon from an extremely radiocarbon-depleted abyssal ocean reservoir that was 'vented' to the atmosphere primarily via the deep-and intermediate overturning loops in the Southern Ocean. While some radiocarbon observations from the intermediate ocean appear to confirm this hypothesis, others appear to refute it. Here we use radiocarbon measurements in paired benthic-and planktonic foraminifera to reconstruct the benthic-planktonic 14 C age offset (i.e. 'ventilation age') of intermediate waters in the western equatorial Atlantic. Our results show clear increases in local radiocarbon-based ventilation ages during Heinrich-Stadial 1 (HS1) and the Younger Dryas (YD). These are found to coincide with opposite changes of similar magnitude observed in the Pacific, demonstrating a 'seesaw' in the ventilation of the intermediate Atlantic and Pacific Oceans that numerical model simulations of North Atlantic overturning collapse indicate was primarily driven by North Pacific overturning. We propose that this Atlantic-Pacific ventilation seesaw would have combined with a previously identified North AtlanticSouthern Ocean ventilation seesaw to enhance ocean-atmosphere CO 2 exchange during a 'collapse' of the North Atlantic deep overturning limb. Whereas previous work has emphasized a more passive role for intermediate waters in deglacial climate change (merely conveying changes originating in the Southern Ocean) we suggest instead that the intermediate water seesaw played a more active role via relatively subtle but globally coordinated changes in ocean dynamics that may have further influenced oceanatmosphere carbon exchange.
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