Switchgrass is a high yielding, low-input intensive, native perennial grass that has been promoted as a major second-generation bioenergy crop. Raw switchgrass is not a readily acceptable feedstock in existing power plants that were built to accommodate coal and peat. The objective of this research was to elucidate some of the characteristics of switchgrass biochar produced via carbonization and to explore its potential use as a solid fuel. Samples were carbonized in a batch reactor under reactor temperatures of 300, 350 and 400 °C for 1, 2 and 3 h residence times. Biochar mass yield and volatile solids decreased from 82.6% to 35.2% and from 72.1% to 43.9%, respectively, by increasing carbonization temperatures from 300 °C to 400 °C and residence times from 1 h to 3 h. Conversely, biochar heating value (HV) and fixed carbon content increased from 17.6 MJ kg and from 22.5% to 44.9%, respectively, under the same conditions. A biomass discoloration index (BDI) was created to quantify changes in biochar colors as affected by the two tested parameters. The maximum BDI of 77% was achieved at a carbonization temperature of 400 °C and a residence time of 3 h. The use of this index could be expanded to quantify biochar characteristics as affected by thermochemical treatments. Carbonized biochar could be considered a high quality solid fuel based on its energy content. OPEN ACCESSEnergies 2014, 7 549
Core Ideas Topographic variation influenced soil nutrient distribution in a silvopasture system. High‐resolution digital maps of soil nutrients were generated. Terrain attributes identified topographic functional units as management zones. Level of soil nutrients in topographic functional units were different. Topography plays a crucial role in spatial distribution of nutrients in soils; however, studies to quantify topographic influence on soil nutrient distribution from a silvopasture system are mostly lacking. To address this question, a 4.3‐ha silvopasture site in northwest Arkansas was selected and a total of 51 topsoil (0–15 cm thickness) samples were collected and analyzed for primary (total N [TN], P, K), secondary (Ca, Mg, S), and micronutrients (Fe, Zn, Cu, Mn, B, Na). Topographic information was acquired from 12 terrain attributes derived from a 1‐m digital elevation model. The prediction model was based on random forest. Results showed TN, S, and P were best predicted, whereas Cu, Ca, and Mn had the lowest prediction performance. Levels of S, Ca, Zn, Fe, and TN increased with SAGA wetness index, valley depth, flow accumulation, and multi‐resolution valley bottom flatness index. Normalized height and slope height were positively related to Na but negatively to B and Cu distribution. Aspect had a positive influence on P and Mg concentrations. Based on terrain attributes, the study site could be divided into four topographic functional units (TFU), namely A, B, C, and D; TFU A had the highest nutrients present, whereas TFU B had the lowest P, K, Zn, Cu, Fe, and Ca but highest Na content. However, Mn, Mg, and B did not vary among TFUs. This study affirmed topographic influences on soil nutrient distribution, and the resulting continuous soil nutrient maps are useful for fine‐tuning production systems through optimum nutrient and pasture management.
Temporal patterns of plant growth, composition, and nutrient removal impact development of models for predicting optimal switchgrass (Panicum virgatum L.) harvest times for bioenergy. Original time-course data are needed to construct useful models. Objectives were to characterize seasonal trends in yield, tissue moisture, ash content, leaf area index (LAI), interception of photosynthetically active radiation (PAR), and macronutrient accumulation and losses. Plots were subjected to 12 single harvests
Dynamic soil chemical interactions with conservation agricultural practices and soil biota are largely unknown. Therefore, this study aims to quantify long‐term (12‐yr) impacts of cover crops, poultry litter, crop rotations, no‐tillage, and their interactions on dynamic soil properties and to determine their relationships with nutrient cycling, crop yield, and soil biodiversity (soil microbial and earthworm communities). Main effects were 13 different cropping sequences of soybean [Glycine max (L.) Merr.], corn (Zea mays L.), and cotton (Gossypium hirsutum L.) at the Research and Education Center at Milan, TN, and eight sequences of corn and soybean at the Middle Tennessee Research and Education Center, Spring Hill, TN. Sequences were repeated in 4‐yr phases from 2002 to 2014. Split‐block cover crop treatments consisted of winter wheat (Triticum aestivum L.), hairy vetch (Vicia villosa Roth), poultry litter, and a fallow control. Soil C and nutrient fluxes were calculated at surface (0–5 cm) and subsurface (5–15 cm) layers during Years 0, 2, 4, 8, and 12. After 12 yr, weighted means (0–15 cm) of soil pH, P, K, Ca, Mg, total N, and C were greater under poultry litter‐amended soils compared with cover crops (P < 0.05). In addition, continuous corn sequences resulted in greater soil K, N, and C concentrations than soybean–soybean–corn–corn rotations (P < 0.05). Poultry litter treatments were positively correlated with greater soil fertility levels, as well as higher crop yield and soil biodiversity. These results underscore linkages between manure additions and cropping sequences, within the nutrient cycling, soil health, and crop production continuum. Core Ideas Bio‐covers illicit greater soil property responses than crop rotations in upper horizons. After 12 yr, cropping rotations affect subsurface physiochemical fluctuations. Soil biodiversity was linked to poultry litter and high‐residue‐producing crops. Poultry litter was the greatest driver for earthworm and microbe community structure. Crop rotation diversity altered soil habitat by influencing nutrient status and residue.
Establishment failures linked to seed dormancy are a challenge to wide‐scale use of switchgrass (Panicum virgatum L.) for biomass feedstock and forage production. One prospective strategy for breaking dormancy is dormant‐season planting. The objectives of this study were to evaluate (i) three switchgrass dormant‐season planting dates (1 December, 1 February, and 15 March) vs. a growing‐season (1 May) control; (ii) two seeding rates (6.7 and 10.1 kg pure live seed [PLS] ha−1); and (iii) high‐ and low‐dormancy seed lots. Treatments were assigned in a split‐plot design with three replications at two locations in Tennessee in 2008 and 2009. Neither seeding rate nor seed‐dormancy level affected plant density or yield (P > 0.05). However, a seeding date × year interaction impacted first‐year density at both locations. Although patterns differed by year for the two locations, density of March plantings equaled or exceeded (P < 0.05) those at other dates for both locations and years. These variations in density did not carry over to impact yield in year two. A sigmoidal regression of seedling density vs. yield was significant (P < 0.001) albeit not strong (R2 = 0.13); yield response approached an asymptote above ∼8 plants m−2. Results suggest March planting dates, using standard seeding rate recommendations (6.7 kg PLS ha−1) irrespective of seed‐dormancy rates, may be more reliable than planting in May. Thus, a broader establishment window than traditionally used may be practical. However, results should be validated over a broader range of soils and climatic conditions, especially over a winter severity gradient.
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