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Green catalytic synthesis of benzimidazoles using Cu metallovesicles as nanoreactors.

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A highly efficient, operationally simple, green catalytic approach using Pd–Ni alloy nanoparticles for Mizoroki Heck coupling.

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An operationally simple and efficient approach for the synthesis of novel spiro‐β‐lactams is described. The key reaction is a halogen‐mediated intrasulfenyl cyclization of a cis‐3‐benzylthio‐3‐(prop‐2‐ynyloxy/‐enyloxy)‐β‐lactam procured through a Lewis acid‐mediated C‐3‐alkylation of the trans‐3‐benzylthio‐3‐chloro‐β‐lactam carbocation equivalent. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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