The competition between an unprecedented reductive chlorination and the Pummerer reaction was studied and applied to the synthesis of benzofused oxygen heterocycles including 3-aminochromanes and in the intramolecular chlorination of activated aromatic rings. The use of (COCl) 2 as a Pummerer activator showed substantial activity, producing α-chlorinated sulfides that can undergo Pummerer−Friedel−Crafts cyclization. If the aromatic ring has electron-donating groups in position three, then the reaction follows a different pathway, yielding the reductive chlorination products, where the chlorine atom comes from a sulfonium salt.
Background: Through the culture of thinness, increasingly promoted in our society as a beauty canon, it is not surprising that the number of people affected by eating disorders is increasing. Objective: This research aims to study the relationship between non-suicidal self-injuries and nuclear aspects of eating disorders specified along with this article. Methods: The sample consisted of 60 women diagnosed with anorexia and bulimia. Questionnaires assessing impulsivity, body satisfaction, alexithymia, body attitude and self-esteem were administered. Participants with non-suicidal self-harm were compared with those without, and participants with anorexia with and without self-harm and participants with bulimia with and without self-harm were compared. Results: Differences were found in body dissatisfaction = 5,71; p ≤ ,01), body attitudes = 4,80; p ≤ ,02), self-esteem = 14,09; p ≤ .00) and impulsivity (t = 3,39; p ≤ ,01) between participants with and without non-suicidal self-harm. Conclusions: These are key factors for the clinic in the treatment of eating disorders to prevent the presence of self-harm, as it allows focusing the treatment target on those aspects such as dissatisfaction and impulsivity, which are key in the development of self-harm.
Even though taking part in elections is one of the most direct tools to influence the sociopolitical system, many people choose not to vote. Research shows that this problem is especially prevalent among those citizens who do not believe they have control over social and political issues, but the question remains as to what could encourage their voting behavior. We predicted that individuals who experience low levels of control can be more susceptible to ingroup norms regarding participation in political elections than those with a high sense of sociopolitical control (SPC). Across six studies, we found consistent support for this hypothesis. Specifically, people who experience decreased SPC were more likely to vote when descriptive norms (measured or manipulated) were conducive to voting. The results have important theoretical and applied implications, illuminating the boundary conditions under which people deprived of control can still be motivated to participate in a political sphere.
Rehabilitation programs for terrorists have gained notoriety. Some issues still require thorough investigation, such as the social support they receive. The present research aims to examine the attitudes towards rehabilitation programs for terrorist offenders and the mediating and moderating mechanisms underlying these attitudes. To this end, two studies were conducted: the first study evaluated the mediating mechanisms (negative feelings and threats; N = 407) and the second study analyzed the moderating mechanisms (social dominance orientation, system justification, and political orientation; N = 444). In both cases, the type of offender was manipulated (criminal vs. nationalist terrorist vs.Islamist terrorist offenders) and different attitudes were assessed (general support, incapacitation, treatment effectiveness, and mandated treatment). The results showed less support for rehabilitation programs for Islamist terrorists than for other offenders. Moreover, Islamist terrorists pose a more significant terrorist threat while criminals pose a greater realistic threat, which led to less favorable attitudes towards rehabilitation programs. Finally, individuals with more conservative ideologies had stronger negative attitudes towards programs for Islamist terrorists. We discuss these findings within the framework of integrated threat and system justification theories.
People desire agentic representations of their personal and collective selves, such as their own nation. When national agency is put into question, this should increase their inclination to restore it, particularly when they simultaneously lack perceptions of personal control. In this article, we test this hypothesis of group-based control in the context of political elections occurring during socio-economic crises. We propose that people who are reminded of low (vs. high) personal control will have an increased tendency to reject traditional political parties that stand for the maintenance of a non-agentic political system. We experimentally manipulated the salience of low vs. high personal control in five studies and measured participants’ intentions to support traditional and new political parties. Across four of five studies, in line with the predictions, low personal control reduced support for the main traditional conservative party (e.g., Partido Popular (PP) in Spain, the Republicans in France). These results appeared in contexts of national economic and/or political crisis, and were most pronounced when low (vs. high) national agency was made salient in Studies 4 and 5. The findings support the notion that rejecting the stability of the national political system can serve as a means to maintain a sense of control through the collective self.
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