A catalyst-free and environmentally friendly process was employed for the production of biodiesel from sea mango seed oil. This oil is non-edible and contains several fatty acids such as palmitic acid (C16), trans-9-elaidic acid (C18:1t), oleic acid (C18:1), linoleic acid (C18:2), and linolelaidic acid (C18:2n6t). The in situ extraction and transesterification of the oil were carried at the subcritical methanol-water condition. The effect of reaction temperature and time on the yield of biodiesel was studied. The maximum yield of biodiesel was 98.58% and achieved at 200 °C, 40 bar and reaction time of 6 h. The ratio among sea mango seed, methanol, and water was 2:10:1.
Organic geochemical studies of Cretaceous formations in the Gongola Basin, northern Nigeria, show TOC values that are generally higher than the minimum (0.5 wt %) required for hydrocarbon generation. Data from Rock‐Eval pyrolysis and biomarker studies indicate the presence of both terrestrial and marine derived Types II and III organic matter, which is immature in the Gombe Formation and of marginal maturity in the Yolde Formation. Immature Type III to IV OM is present in the Pindiga Formation; and Type III OM, with a maturity that corresponds to the conventional onset (or perhaps peak) of oil generation occurs in the Bima Formation. However, Bima Formation samples from the 4710 – 4770 ft (1435.6 – 1453.9 m) depth interval within well Nasara‐1 indicate Type I OM of perhaps lacustrine origin (H31R/H30 ratio generally ≤0.25).
Although the Nasara‐1 well was reported to be dry, geochemical parameters (high TOCs, S1, S2 and Hls, low Tmax compared to adjacent samples, a bimodal S2 peak on the Rock‐Eval pyrogram, a dominance of fluorinite macerals), together with generally low H3IR/H30 biomarker ratios within the 4710–4770 ft (1435.6–1453.9 m) interval, suggest the presence of migrated oil, perhaps sourced by lacustrine shales in the Albian Bima Formation located at as‐yet unpenetrated depths.
The presence of the migrated oil in the Bima Formation and its possible lacustrine origin suggest that the petroleum system in the Gongola Basin is similar to that of the Termit, Doba and Doseo Basins of the Chad Republic, where economic oil reserves have been encountered.
Abundant coal resources that were previously neglected due to a crude oil boom need revitalisation and integration into the national electricity mix to address the energy demands of the Nigerian population. Selected coal samples from the Benue Trough sedimentary basin in Nigeria were examined by various techniques, including proximate and ultimate analyses, organic petrography, Fourier transform infrared ray spectroscopy, and thermogravimetric analysis. Based on vitrinite reflectance, the Lafia-Obi (OLB), Garin Maiganga (GMG), Imiegba (IMG), and Okaba (OKB) coals are classified as subbituminous, while the Lamja1 (LMJ1), Lamja2 (LMJ2) and Chikila (CHK) coals are high volatile B bituminous. The Enugu (ENG) coal is on the boundary between subbituminous and high volatile C bituminous. Organic petrographic results indicate vitrinite and fusinite contents steadily increase from the Lower Benue Trough coals to the Upper Benue Trough coals, while semifusinite and total mineral contents follow a reverse pattern. Thermal decomposition occurred in three stages, i.e., drying, devolatilization, and coke formation above 700°C; and the coal reactivity follows the following order, ENG [IMG[IGH[CHK[LMJ[OKB[GMG[LFB. The higher temperatures (above 900°C) are required to decompose the coals for efficient energy recovery. The LMJ1, LMJ2, OLB, CHK, GMG, and OKB coals can be exploited for electricity power generation. However, the Imeagha and Enugu coals are best suitable for both cement and power generation.
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