Thermodynamic and mass balance studies of Pb(II) and Cu(II) biosorption from aqueous solution using chicken feathers (CF) were carried out. Thermodynamic parameters such as standard free energy (ΔG0), enthalpy (ΔH0) and entropy (ΔS0) changes were calculated from the data obtained to predict the nature of adsorption by chicken feathers (CF). From the results, entropy changes were positive indicating an increase in disorderliness in the adsorption of Pb(II) and Cu(II) onto the chicken feathers (CF). The negative values of Gibbs free energy and positive values of enthalpy indicated that the adsorption process by CF was spontaneous and endothermic. Data obtained also showed that the percentage Cu(II) and Pb(II) released by CF after digestion at 25 mg/l were higher than those released at 100 mg/l. Finally, FTIR analysis confirmed the presence of carboxyl, hydroxyl, amino and sulphur containing functional groups on CF, with no substantial variation in the spectra obtained before and after adsorption indicating a possible re use of CF.
This study was carried out to examine the adsorption isotherm (Langmuir, Freundlich, Temkin, and Dubinin Radushkevich adsorption isotherm) of Pb(II) and Cu(II) in order to determine the maximum adsorption capacity of chicken feather, CF. Equilibrium sorption of Pb(II) and Cu(II) using homogeneously sized Chicken Feather (CF) was carried out and the physico-chemical properties of the feathers were determined. Results revealed that the maximum biosorption capacity of Pb(II) and Cu(II) by the chicken feather from Langmuir isotherm model were 79.36 and 61.92 mg/g respectively. Separation factor RL were 0.195 and 0.018 indicating a favourable adsorption process. Mean free energy (E) from Dubinin Radushkevich isotherm model were 1.291 and 0.102 KJ/mol for Pb(II) and Cu(II) respectively, indicating a physical adsorption process. Negative standard Gibbs free energy (ΔG) obtained indicated that the Pb(II) biosorption process was spontaneous and thermodynamically feasible.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.