In this paper, a coupled optical-electrical modeling method is applied to simulate perovskite solar cells (PSCs) to find ways to improve light absorption by the active layer and ensure that the generated carriers are collected effectively. Initially, a planar structure of the PSC is investigated and its optical losses are determined. To reduce the losses and enhance collection efficiency, a convex light-trapping configuration of PSC is used and the impacts of these nanostructures on all parts of the cell are investigated. In this convex nanostructured PSC, the power conversion efficiency (PCE) is found to be increased when the thickness of the absorbing layer remained unchanged. Then, a plasmonic reflector is applied to trap light inside the perovskite. In this structure, by scattering light through the surface plasmon resonance (SPR) effect of the Au back-contact, the electromagnetic field is found to concentrate in the active layer. This results in increased perovskite absorption and, consequently, a high current density of the cell. In the final structure, which is the integration of these two structures, optical losses are found to be greatly diminished and the short-circuit current density (Jsc) is increased from 18.63 mA/cm2 for the planar structure to 23.5 mA/cm2 for the proposed structure. Due to the increased Jsc and open-circuit voltage (Voc) caused by the improved carrier collection, the PCE increases from 14.62 to 19.54%.
In this paper, a nanostructured perovskite solar cell (PSC) on a textured silicon substrate is examined, and its performance is analyzed. First, its configuration and the simulated unit cell are discussed, and its fabrication method is explained. In this proposed structure, poly-dimethylsiloxane (PDMS) is used instead of glass. It is shown that the use of PDMS dramatically reduces the reflection from the cell surface. Furthermore, the light absorption is found to be greatly increased due to the light trapping and plasmonic enhancement of the electric field in the active layer. Then, three different structures, are compared with the main proposed structure in terms of absorption, considering the imperfect fabrication conditions and the characteristics of the built PSC. The findings show that in the worst fabrication conditions considered structure (FCCS), short-circuit current density (Jsc) is 22.28 mA/cm2, which is 27% higher than that of the planar structure with a value of 17.51 mA/cm2. As a result, the efficiencies of these FCCSs are significant as well. In the main proposed structure, the power conversion efficiency (PCE) is observed to be improved by 32%, from 13.86% for the planar structure to 18.29%.
In this paper, coupled optical and electrical simulations of perovskite solar cells (PSCs) are performed to optimize their basis output parameters and obtain the best power conversion efficiency (PCE) based on both the light absorption and carrier transport mechanisms. Due to the limitations of perovskite absorption in longer wavelengths, we used an extra photo-active material of GeSe with a narrower bandgap and a broader absorbing spectrum to increase the efficiency of the PSC. To prevent carrier transmission disorder that exists in the planar structure with two absorbing materials, GeSe was inserted into the main active layer in the form of nanowires (NWs). As a result, it improved the carrier transfer and open-circuit voltage (V oc ) in addition to the short-circuit current density (J sc ). The behavior of PSC with different sizes of GeSe NWs at the same density was investigated to determine the appropriate size of NWs and achieve the highest PCE. In the optimal structure with 50 nm diameter NWs, J sc and PCE of the cell are 22.96 mA cm −2 and 18.97%, which are improvements of 39% and 50%, respectively, compared to the planar structure studied at the beginning of the paper.
The incomplete absorption of light in the Perovskite Solar Cells (PSCs) due to the escape of the photons and the waste of their energy in the visible spectrum hinders the efficiency of this type of solar cell. Utilizing light-trapping nanostructures and stimulating the device’s plasmonic is an efficient way to increase absorption and reduce the energy losses. In this paper, a novel configuration of a nanostructured PSC with a plasmonic enhancement has been introduced to confine light in the active layer and boost energy harvesting. According to the conducted calculations, the modified configuration supports 23% higher short-circuit current density (JSC) and 21% Power Conversion Efficiency (PCE) compared to the conventional PSC. In this study, the Finite Element Method (FEM) has been employed to perform numerical simulations of the examined structures. For modeling and characterizing solar cells, optical physics of the devices is used in conjunction with their electrical physics.
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