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Studies of OAE 2 sections beyond the Atlantic Ocean, Western Interior Seaway (WIS) and European pelagic shelf are limited. Here, we present initial osmium isotope stratigraphy ( 187 Os/ 188 Os-Os i ) from two proto-Pacific sites that span the Cenomanian-Turonian boundary interval (CTBI): the Yezo Group (YG) section, Hokkaido, Japan, and the Great Valley Sequence (GVS), California, USA; to evaluate the 187 Os/ 188 Os seawater chemistry of the proto-Pacific. Additionally we combine new 206 Pb/ 238 U zircon CA-ID-TIMS geochronology from five volcanic tuff horizons of the Yezo Group section to test and facilitate inter-basinal integration with the WIS using radio-isotopically constrained age-depth models for both sections, and quantitatively constrain the absolute timing and duration of events across the CTBI. The YG shows an almost identical Os i profile to that of the WIS, and very similar to that of other sites of the proto-Atlantic and European pelagic oceans (Turgeon and Creaser, 2008;Du Vivier et al., 2014). The characteristics of the Os i profile are radiogenic and heterogeneous (∼0.55-0.85) prior to the OAE 2, and synchronous with the inferred OAE 2 onset the Os i abruptly become unradiogenic and remain relatively homogeneous (∼0.20-0.30) before showing a gradual return to more radiogenic Os i (∼ 0.70) throughout the middle to late OAE 2. A 206 Pb/ 238 U zircon age of an interbedded tuff (HK017) in the adjacent horizon to the first unradiogenic Os i value constrains the age of the Os i inflection at 94.44 ± 0.14 Ma. This age, including uncertainty, agrees with the interpolated age of the same point in the Os i profile (94.28 ± 0.25 Ma) in the only other dated OAE 2 section, the WIS; indicating a coeval shift in seawater chemistry associated with volcanism at the OAE 2 onset at the levels of temporal resolution (ca. 0.1 Myr). Further, prior to the onset of OAE 2 an enhanced radiogenic inflection in the Os i profile of the YG is correlative, within uncertainty, with a similar trend in the WIS based on the U-Pb agedepth model. The interpolated ages, 94.78 ± 0.12 Ma and 94.66 ± 0.25 Ma for this Os i inflection in the YG and WIS, respectively, indicate that palaeocirculation was sufficient to simultaneously influence transbasinal seawater chemistry. In contrast, the pre-OAE 2 Os i profile for the GVS is disparate to that of the YG and those of the proto-Atlantic and European pelagic shelf locations. We interpret the pre OAE 2 heterogeneous Os i values (0.30-0.95) to record a palaeobasin that was regionally influenced interchangeably by both unradiogenic (hydrothermal flux) and radiogenic (continental flux) Os. We conclude that the Os i profiles from the proto-Pacific sections record both trends that are consistent globally (OAE 2 onset, syn and post OAE 2), but also show regional differences (pre OAE 2) between OAE 2 sections worldwide. As such the Os i profiles coupled with U-Pb geochronology facilitate the correlation of OAE 2 stratigraphy, and demonstrate both regional and global ocean dynamics.

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Abstract. Antarctic sea ice plays a critical role in the Earth system, influencing energy, heat and freshwater fluxes, air–sea gas exchange, ice shelf dynamics, ocean circulation, nutrient cycling, marine productivity and global carbon cycling. However, accurate simulation of recent sea-ice changes remains challenging and, therefore, projecting future sea-ice changes and their influence on the global climate system is uncertain. Reconstructing past changes in sea-ice cover can provide additional insights into climate feedbacks within the Earth system at different timescales. This paper is the first of two review papers from the Cycles of Sea Ice Dynamics in the Earth system (C-SIDE) working group. In this first paper, we review marine- and ice core-based sea-ice proxies and reconstructions of sea-ice changes throughout the last glacial–interglacial cycle. Antarctic sea-ice reconstructions rely mainly on diatom fossil assemblages and highly branched isoprenoid (HBI) alkenes in marine sediments, supported by chemical proxies in Antarctic ice cores. Most reconstructions for the Last Glacial Maximum (LGM) suggest that winter sea ice expanded all around Antarctica and covered almost twice its modern surface extent. In contrast, LGM summer sea ice expanded mainly in the regions off the Weddell and Ross seas. The difference between winter and summer sea ice during the LGM led to a larger seasonal cycle than today. More recent efforts have focused on reconstructing Antarctic sea ice during warm periods, such as the Holocene and the Last Interglacial (LIG), which may serve as an analogue for the future. Notwithstanding regional heterogeneities, existing reconstructions suggest that sea-ice cover increased from the warm mid-Holocene to the colder Late Holocene with pervasive decadal- to millennial-scale variability throughout the Holocene. Studies, supported by proxy modelling experiments, suggest that sea-ice cover was halved during the warmer LIG when global average temperatures were ∼2 ∘C above the pre-industrial (PI). There are limited marine (14) and ice core (4) sea-ice proxy records covering the complete 130 000 year (130 ka) last glacial cycle. The glacial–interglacial pattern of sea-ice advance and retreat appears relatively similar in each basin of the Southern Ocean. Rapid retreat of sea ice occurred during Terminations II and I while the expansion of sea ice during the last glaciation appears more gradual especially in ice core data sets. Marine records suggest that the first prominent expansion occurred during Marine Isotope Stage (MIS) 4 and that sea ice reached maximum extent during MIS 2. We, however, note that additional sea-ice records and transient model simulations are required to better identify the underlying drivers and feedbacks of Antarctic sea-ice changes over the last 130 ka. This understanding is critical to improve future predictions.

Abstract. Antarctic sea ice plays a critical role in the Earth system, influencing energy, heat, and freshwater fluxes, air-sea gas exchange, ice shelf dynamics, ocean circulation, nutrient cycling, marine productivity, and global carbon cycling. However, accurate simulation of recent sea-ice changes remains challenging, and therefore projecting future sea-ice changes and their influence on the global climate system is uncertain. Reconstructing past changes in sea-ice cover can provide additional insights into climate feedbacks within the Earth system at different timescales. This paper is the first of two review papers from the Cycles of Sea Ice Dynamics in the Earth system (C-SIDE) Working Group. In this first paper, we review marine- and ice core-based sea-ice proxies and reconstructions of sea-ice changes throughout the last glacial-interglacial cycle. Antarctic sea-ice reconstructions rely mainly on diatom fossil assemblages and highly branched isoprenoid (HBI) alkenes in marine sediments, supported by chemical proxies in Antarctic ice cores. Most reconstructions for the Last Glacial Maximum (LGM) suggest winter sea-ice expanded all around Antarctica and covered almost twice its modern surface extent. In contrast, LGM summer sea-ice expanded mainly in the regions off the Weddell and Ross seas. The difference between winter and summer sea ice during the LGM led to a larger seasonal cycle than today. More recent efforts have focused on reconstructing Antarctic sea-ice during warm periods, such as the Holocene and the Last Interglacial (LIG), which may serve as an analogue the future. Notwithstanding regional heterogeneities, existing reconstructions suggest sea-ice cover increased from the warm mid-Holocene to the colder Late Holocene, with pervasive decadal-to-millennial scale variability throughout the Holocene. Sparse marine and ice core data, supported by proxy modelling experiments, suggest that sea-ice cover was halved during the warmer LIG, when global average temperatures were ~2 °C above the pre-industrial (PI). There are limited marine (14) and ice core (4) sea-ice proxy records covering the complete 130,000 year (130 ka) last glacial cycle. The glacial-interglacial pattern of sea-ice advance and retreat appears relatively similar in each basin of the Southern Ocean. Rapid retreat of sea ice occurred during Terminations II and I, while the expansion of sea ice during the last glaciation appears more gradual, especially in cores data sets. Marine records suggest that the first prominent expansion occurred during Marine Isotope Stage (MIS) 4 and that sea ice reached maximum extent during MIS 2. We however note that additional sea-ice records and transient model simulations are required to better identify the underlying drivers and feedbacks of Antarctic sea-ice changes over the last 130 ka. This understanding is critical to improve future predictions.

No abstract