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Background: Cadmium (Cd) is a toxic heavy metal that affects plant growth and human health. Therefore, it is necessary to reduce its concentration. Objectives: This research was done to investigate the role of tire rubber ash enriched cow manure application to reduce Cd uptake by canola. Methods: Treatments were consist of applying three levels of cow manure (0, 10 and 20 t ha-1), two levels of tire rubber ash (0 and 200 kg ha-1) in a Cd polluted soil (0, 5, 10 and 15 mg Cd (kg soil)-1). The Cd and Zinc (Zn) concentration of canola was measured using atomic absorption spectroscopy. This research was done as a factorial experiment in the layout of completely randomized block design with three replications. Results: Applying 20 t ha-1 tire rubber ash enriched cow manure in 10 mg Cd (kg soil)-1 polluted soils decreased root Cd concentration by 30.1%, while the root Zn concentration was increased by 17%. In addition, applying the above amount of organic amendment in 15 mg Cd (kg soil)-1 polluted soils decreased grain Cd concentration by 45.7%, while the grain Zn concentration was increased by 27%. In addition, the aboveground biomass of plant was also increased by 30%. Conclusions: The results of this study showed that enrichment of cow manure with tire rubber ash can decrease plant Cd concentration in Cd polluted soils (interaction effects of Cd and Zn), that is a positive point in environmental research. However, the type of plant and amount of pollution could not be ignored.

Lead I 4900 Synthesis and Characterization of Two New Fluoroplumbate(II) Complexes: Tetrabutylammonium Fluorodihaloplumbate, (Bu) 4 N[PbX 2 F] (X: Cl, I). -The new title compounds are synthesized by reaction of PbCl2 or PbI2 with Bu4NF in MeCN (20°C, 24 h). The samples are characterized by IR, UV/VIS, 13 C, 1 H, and 19 F NMR spectroscopy. There is no side product and the reaction is quite fast. The accompanying color change provides visual means for ascertaining the progress of the reaction. -(JAVANSHIR, Z.; MEHRANI, K.; GHAMMAMY*, S.; SAGHATFOROUSH, L.; SEYEDSADJADI, S.; HASSANIJOSHAGHANI, A.; TAVAKOL, H.; Bull. Korean Chem.

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