The quest to enhance public health and the need for a reduction in the environmental solid wastes have prompted this study. Despite abundant studies on silica fume (SF or S) and waste glass powder (WGP or G), there is a need to understand the interaction of WGP with SF in the production of ordinary Portland cement (OPC or C)-based concrete using the water/binder ratio of 0.42. The investigated concrete comprised 90 wt.% of OPC and 10 wt.% of WGP+SF. The samples were denoted as C90GxS10−x such that x varied from 0–10 wt.% at the interval of 2.5. The findings revealed that an increase in the WGP/SF ratio enhanced the absorption of silica/glass blended concrete due to size incompatibility and proliferations of interfacial transition zones between the glass particle, silica fume and cement matrix. The density of fresh OPC concrete was higher than that of glass/silica blended concrete due to the difference in their relative densities. Incorporating WGP and SF in synergy enhanced silicate reorganization and led to a more amorphous binder and a reduction in hydroxyl-based compounds such as portlandite but caused microstructural heterogeneity in the morphology of the binder as obtained from XRD, FTIR and SEM/EDS results. The 28-day compressive strength of 46 MPa is achievable if the WGP and SF are kept within 2.5–5 wt.% and 5–7.5 wt.%, respectively. The study will foster the production of economic, environmental, and cost-efficient concrete.
Identifying the causes of road traffic crashes (RTCs) and contributing factors is of utmost importance for developing sustainable road network plans and urban transport management. Driver-related factors are the leading causes of RTCs, and speed is claimed to be a major contributor to crash occurrences. The results reported in the literature are mixed regarding speed-crash occurrence causality on rural and urban roads. Even though recent studies shed some light on factors and the direction of effects, knowledge is still insufficient to allow for specific quantifications. Thus, this paper aimed to contribute to the analysis of speed-crash occurrence causality by identifying the road features and traffic flow parameters leading to RTCs associated with driver errors along an access-controlled major highway (761.6 km of Highway 15 between Taif and Medina) in Saudi Arabia. Binomial logistic regression (BNLOGREG) was employed to predict the probability of RTCs associated with driver errors (p < 0.001), and its results were compared with other supervised machine learning (ML) models, such as random forest (RF) and k-nearest neighbor (kNN) to search for more accurate predictions. The highest classification accuracy (CA) yielded by RF and BNLOGREG was 0.787, compared to kNN’s 0.750. Moreover, RF resulted in the largest area under the ROC (a receiver operating characteristic) curve (AUC for RF = 0.712, BLOGREG = 0.608, and kNN = 0.643). As a result, increases in the number of lanes (NL) and daily average speed of traffic flow (ASF) decreased the probability of driver error-related crashes. Conversely, an increase in annual average daily traffic (AADT) and the availability of straight and horizontal curve sections increased the probability of driver-related RTCs. The findings support previous studies in similar study contexts that looked at speed dispersion in crash occurrence and severity but disagreed with others that looked at absolute speed at individual vehicle or road segment levels. Thus, the paper contributes to insufficient knowledge of the factors in crash occurrences associated with driver errors on major roads within the context of this case study. Finally, crash prevention and mitigation strategies were recommended regarding the factors involved in RTCs and should be implemented when and where they are needed.
The need to get rid of solid waste in the environment necessitates the incorporation of waste glass powder (WGP) in mortar and concrete. The blending of WGP (G) with ordinary Portland cement (OPC) is a valorization technique that is not only cost efficient but also environmentally friendly. The replacement level is denoted as CxG10−x, where x is 0–20 wt.% at an interval of 5 wt.% in mortar (w/b = 0.4) and 0, 10, 20 and 30 in concrete (w/b = 0.42). The study investigates the effects of glass on the setting, workability, thermal resistance, microstructure, mineral phases and bond characteristics of silicon and hydroxyl-based compounds and C-O vibrations. It also provides the model equations for strength characteristics in terms of OPC, G and ages in mortar and concrete on one hand and investigates the residual strength and density of glass blended concrete at elevated temperature (550 °C) on the other. It is found that glass enhances the workability, reduces the setting time and density and enhances the residual strength and density of concrete. The presence of glass leads to the formation of coesite and microstructural distortion and decreases the Ca/Si ratio. Besides, the bond characteristics of the binder are significantly affected, while the thermal residual strength capacity in glass blended concrete (C80G20) is 40.4% and 75.14% lower than that in OPC concrete (C100G0) because of the low thermal conduction of glass particles. The optimum glass content in mortar and concrete to produce 33 MPa (28 days) and 47 MPa (90 days) is found to be 10 wt.% and 20 wt.%, respectively.
The development of sustainable, environmentally friendly alkali-activated binder has emerged as an alternative to ordinary Portland cement. The engineering and durability properties of alkali-activated binder using various precursor combinations have been investigated; however, no study has focused on the impact of high-volume natural pozzolan (NP) on the acid resistance of alkali-activated NP and limestone powder. Therefore, the current study assesses the impact of high-volume natural pozzolan (volcanic ash) on the durability properties of alkali-activated natural pozzolan (NP) and limestone powder (LSP) mortar by immersion in 6% H2SO4 for 365 days. The samples were prepared with different binder ratios using alkaline activators (10 M NaOH(aq) and Na2SO4) combined in a 1:1 ratio and cured at 75 . NP was combined with the LSP at three different combinations: NP:LSP = 40:60 (AAN40L60), 50:50 (AAN50L50), and 60:40 (AAN60L40), representing low-volume, balanced, and high-volume binder combinations. Water absorption, weight change, and compressive strength were examined. The microstructural changes were also investigated using FTIR, XRD, and SEM/EDS characterization tools. Visual examination showed insignificant deterioration in the sample with excess natural pozzolan (AAN60L40) after 1 year of acid exposure, and the maximum residual strengths were 20.8 MPa and 6.68 MPa in AAN60L40 and AAN40L60 with mass gain (1.37%) and loss (10.64%), respectively. The high sulfuric acid resistance of AAN60L40 mortar was attributed to the high Ca/Si = 10 within the C-A-S-H and N-A-S-H formed. The low residual strength recorded in AAN40L60 was a result of gypsum formation from an acid attack of calcium-dominated limestone powder. The controlling factor for the resistance of the binder to acid corrosion was the NP/LSP ratio, whose factor below 0.6 caused significant debilitating effects.
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