Synthetic approach to a new substituted tetrathieno [2,3-b]porphyrazine, its planar and sandwich-type complexes was developed. Aggregation phenomena and spectral properties of the target compounds were investigated by UVVis spectroscopy and AFM. Electrochemical behaviour of the Zn complex was studied in a wide range of potentials (-2.0÷2.0 V). The NLO properties of Zn complex was studied by the z-scan approach.
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