Electrochemical formation of self-organized TiO2 nanotube layers has been a highly active research field for more than 10 years. In the present manuscript we investigate the formation of two distinctly different anodic TiO2 nanotube morphologies, 'single walled' and 'double walled' tubes, which are formed mainly depending on the nature of the anodization electrolyte. While the widest used electrolytes are ethylene glycol (EG) based, forming double walled structures, tubes formed in dimethyl sulfoxide (DMSO) based electrolytes show a single tube walled morphology. Here we provide reasons for the formation of double walled tubes, characterize tubes for their composition, structure and certain properties, and give measures to suppress or minimize double wall formation. Except for the fact that in DMSO single walled tubes are formed, we also show that they grow sufficiently slowly to allow partial crystallization of the tubes during growth--this, in turn drastically influences their electronic properties. Finally we discuss the effects and potential consequences of double or single wall growth for TiO2 nanotube applications.
Host-guest systems such as hematite/SnO2 have attracted a great deal of interest as photoanodes for photoelectrochemical water splitting. In the present work we form an ordered porous tin oxide layer formed by self-organizing anodization of Sn films on a FTO substrate. Subsequently the anodic tin oxide nanostructure is doped with antimony (ATO) by a simple impregnation and annealing treatment, and then decorated with hematite using anodic deposition. Photoelectrochemical water splitting experiments show that compared to conventional SnO2 nanostructures, using a Sb doped nanochannel SnO2 as a host leads to a drastic increase of the water splitting photocurrent response up to 1.5 mA cm(-2) at 1.6 V (vs. RHE) in 1 M KOH under AM 1.5 (100 mW cm(-2) ) conditions compared to 0.04 mA cm(-2) for the non-Sb doped SnO2 scaffold.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.