The change of the organic bone cements�composition (COO) determines the adjustment of some important properties for the behaviour as fixing material, such as the: superficial tension, polarity, surface energy, viscosity, contraction at polymerisation, porosity. In the present paper we monitored the influence of the composition�s changes for some acrylic cements upon their handling features. The samples were obtained via the partial replacement of the methyl methacrylate (MMA) in the liquid phase of some usual formulas with another acrylic monomer. For these, it was measured the contact angles as wettablility of the fixing material. Moreover, it was estimated the values of the hardening time, important parameter for the application phases of the cements with cold hardening and fixing of the articular endoprostheses.
Successfully used in bone surgery for more than 65 years, self-hardening organic cements (CCOs), in particular acrylic cements, are today, the most advanced complementary biomaterials used in articular endoprosthesis. One of the strategies for obtaining of performing anchorage of artificial implants is to develop new acrylic cements with improved physical, chemical and biomechanical characteristics. The aim of this paper was to identify the compositional and morpho-structural changes of acrylic cements induced by the composition of the liquid phase of the material. Such changes influence the potential to generate the physical bonds responsible for fixation and stabilization of endoprosthesis. The samples studied had different compositions due to the mixture of acrylic monomers, methyl methacrylate (MMA) and butyl acrylate (BuA) in the liquid component of cement. The MMA / BuA ratio varied between 1/0 v / v and 1/4 v / v. Changes in the composition and morphology of cement samples have been highlighted by ESCA (Electron Spectroscopy for Chemical Analysis), EDX (Energy-Dispersive X-ray Spectroscopy), IR spectroscopy and SEM images. The obtained data show that minor changes in cement composition can significantly influence morpho-structural characteristics such as pore size and their distribution in the mass of fixing material.
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