This study investigated levels and sources of pollution and potential health risks associated with potentially toxic elements (PTEs) and polycyclic aromatic hydrocarbons (PAHs) in urban street dust collected from Tyumen city, a large transport centre with one of the highest motorization rates in Russia. Twenty street dust samples were collected from four grades of roads in five different land use areas.Research methods included measurements of physical and chemical properties of street dust, concentrations of 18 PTEs using inductively coupled plasma mass spectrometry, 12 PAHs using high-performance liquid chromatography, and statistical analysis of the data. Concentrations of Ni, Cr, Sb, and Mo, as well as medium and high molecular weight PAHs in urban street dust, were notably higher than in soils within the city, which indicates that transport is the main source of these elements. Concentrations of Cu, Cd, Pb, Zn, Mn, and As in street dust of Tyumen were lower compared to many large cities, while Cr, Ni, and Co were higher. Concentrations of PAH were comparable to other large nonindustrial cities. Total contamination of street dust by both PTEs and PAHs showed more robust relationships with the number of roadway lanes rather than land use. The estimated carcinogenic risks were low in 70% of samples and medium in 30% of samples. Noncarcinogenic risks were attributed to exposure to Co, Ni, V, and As. The total noncarcinogenic risk for adults was found to be negligible, while the risk was found to be moderate for children.
Buried soils within aeolian deposits are considered an important tool for diagnosing, determining the age, and estimating the intensity of aeolian processes at the transition from the Pleistocene to the Holocene in the Northern Hemisphere. Late Pleistocene aeolian coversands and ancient inland dunes are widely distributed in the periglacial zone of Western Siberia. In contrast to the territories of Central and Eastern Europe, the paleosol archive of the aeolian sands and dunes of Western Siberia has not yet been studied. This paper presents the first findings of late Pleistocene paleosols within the ancient inland dunes in the southeast of Western Siberia (Ob–Tomsk interfluve, Tomsk region). The soils and their stratigraphic position were studied in the outcrop of the quarry, located in the junction zone of the second Tom river terraces and the ancient valley. Two types of paleosols were identified. The first one is confined to the central part of a small dune and is represented by a slightly developed Albic Arenosol with fragmentary humus horizon Ahb and a well-pronounced Eb. It can probably be considered as an analogue of the European Usselo soil. The second paleosol was found at the bottom of the interdune depression. It is represented by a brown Bwb horizon and probably corresponds to a Brunic Arenosol (Dystric). The second paleosol is characterized by a higher content of clay fraction and organic carbon, the presence of weak signs of illuviation, and richer and more diverse mineral composition. This soil is apparently an analogue of the European Finow soil. Radiocarbon dating of the charcoals found in the paleosols suggests that the first dates from the Younger Dryas (ca. 12,036 cal. yr. BP), and the second one from the Allerød (ca. 13,355 cal. yr. BP). The study results propose that the natural environment in the periglacial zone of the south of Western Siberia was generally similar to those in Central and Eastern Europe, and the activation of aeolian processes, which led to the formation of a dune relief, occurred at about the same time.
The paper presents the results of studying the development of calcite neoformations on the surfaces of modern buildings within the city of Tyumen. The objects of the study were carbonate crusts and stalactite-like bodies formed on the surfaces of five representative buildings in the city center. Research methods included visual diagnostics, optical microscopy, scanning electron microscopy with energy dispersive X-ray spectroscopy, confocal laser scanning microscopy and semi-quantitative determination of the mineral composition by X-ray diffraction analysis. The results of the study show that calcite is the main component of all carbonate crusts, while other minerals were found in small quantities. The microscopic studies revealed the differences in morphology of crusts developing on horizontal and vertical surfaces. The mycelium of fungi (presumably of the Penicillium group), represented by filamentous and often hollow hyphae covered with calcite, as well as relics of bacterial colonies were found in all studied samples. It was noted that the mycelium forms the structural frame of carbonate crusts and stalactites. Studies have shown that the prokaryotic–eukaryotic communities are responsible for the high rate of the urban speleothem growth and play the main role in calcite precipitation at the initial stages of their development.
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