The evaporation of a liquid drop on a solid substrate is a remarkably common phenomenon. Yet, the complexity of the underlying mechanisms has constrained previous studies to spherically symmetric configurations. Here we investigate well-defined, non-spherical evaporating drops of pure liquids and binary mixtures. We deduce a universal scaling law for the evaporation rate valid for any shape and demonstrate that more curved regions lead to preferential localized depositions in particle-laden drops. Furthermore, geometry induces well-defined flow structures within the drop that change according to the driving mechanism. In the case of binary mixtures, geometry dictates the spatial segregation of the more volatile component as it is depleted. Our results suggest that the drop geometry can be exploited to prescribe the particle deposition and evaporative dynamics of pure drops and the mixing characteristics of multicomponent drops, which may be of interest to a wide range of industrial and scientific applications.

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The dynamics of a slender, evaporating, particle-laden droplet under the effect of electric fields are examined. Lubrication theory is used to reduce the governing equations to a coupled system of evolution equations for the interfacial position and the local, depth-averaged particle concentration. The model incorporates the effects of capillarity, viscous stress, Marangoni stress, elecrostatically induced Maxwell stress, van der Waals forces, concentration-dependent rheology, and evaporation. Via a parametric numerical study, the one-dimensional model is shown to recover the expected inhomogeneous ring-like structures in appropriate parameter ranges due to a combination of enhanced evaporation close to the contact line, and resultant capillarity-induced flow. It is then demonstrated that this effect can be significantly suppressed via the use of carefully chosen electric fields. Finally, the three-dimensional behavior of the film and the particle concentration field is briefly examined.

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