Cellulose emerges as an alternative for the treatment of water contaminated with heavy metals due to its abundant biomass and its proven potential in the adsorption of pollutants. The aquatic plant Eichhornia crassipes is an option as raw material in the contribution of cellulose due to its enormous presence in contaminated wetlands, rivers, and lakes. The efficiency in the removal of heavy metals is due to the cation exchange between the hydroxyl groups and carboxyl groups present in the biomass of E. crassipes with heavy metals. Through different chemical and physical transformations of the biomass of E. crassipesThe objective of this review article is to provide a discussion on the different mechanisms of adsorption of the biomass of E. crassipes to retain heavy metals and dyes. In addition to estimating equilibrium, times through kinetic models of adsorption and maximum capacities of this biomass through equilibrium models with isotherms, in order to design one biofilter for treatment systems on a larger scale represented the effluents of a real industry.
The transport sector powered by internal combustion engines (ICE) requires novel approaches to achieve near-zero CO2 emissions. In this direction, using CO2 capture and storage (CCS) systems onboard could be a good option. However, CO2 capture in mobile sources is currently challenging due to the operational and space requirements to install a CCS system onboard. This paper presents a systematic review of the CO2 capture in ICE driven transport to know the methods, techniques, and results of the different studies published so far. Subsequently, a case study of a CCS system working in an ICE is presented, where the energy and space needs are evaluated. The review reveals that the most suitable technique for CO2 capture is temperature swing adsorption (TSA). Moreover, the sorbents with better properties for this task are PPN-6-CH2-DETA and MOF-74-Mg. Finally, it shows that it is necessary to supply the energy demand of the CCS system and the option is to take advantage of the waste heat in the flue gas. The case study shows that it is possible to have a carbon capture rate above 68% without affecting engine performance. It was also found that the total volume required by the CCS system and fuel tank is 3.75 times smaller than buses operating with hydrogen fuel cells. According to the review and the case study, it is possible to run a CCS system in the maritime sector and road freight transport.
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