An orthorhombic compound, NaMnSbO 4 , represents a square net of magnetic Mn 2+ ions residing in vertex-shared oxygen octahedra. Its static and dynamic magnetic properties were studied using magnetic susceptibility, specific heat, magnetization, electron spin resonance (ESR), nuclear magnetic resonance (NMR) and density functional calculations. Thermodynamic data indicate an establishment of the long-range magnetic order with T N ~ 44 K, which is preceded by a short-range one at about 55 K. In addition, a non-trivial wasp-waisted hysteresis loop of the magnetization was observed, indicating that the ground state is most probably canted antiferromagnetic. Temperature dependence of the magnetic susceptibility is described reasonably well in the framework of 2D square lattice model with the main exchange parameter J =-5.3 K, which is in good agreement with density functional analysis, NMR and ESR data.
We demonstrate an experimental method for the improvement of the magnetic field homogeneity in Halbach magnets by taking magnet material imperfection into account. This method relies on the determination of the magnetization magnitude only for individual magnet blocks based on nuclear magnetic resonance field measurements in a simplified system, which, in our case, consists of four blocks. Then, a set of configurations with highest homogeneities can be found from simplified field map simulations of all possible configurations or by applying sophisticated optimum search algorithms if the number of blocks is large. Finally, the residual effect of angular magnetization deviations can be reduced by the experimental selection of the best configuration from the set found on the simulation step. This selection strategy is based on the conclusions made from statistical analysis of simulated field maps. By applying the described method to our eight-element magnet, we experimentally achieved tenfold field homogeneity improvement. Thus, in the best configuration, we obtained an average value of the magnetic field of 598.0 mT and a half-width of 226.9 ppm for a sample with a diameter of 4 mm and a height of 10 mm. These parameters along with the compact magnet size (40 × 40 × 102 mm3) and weight (0.6 kg) provide reasonable magnet quality compared with analogous systems having more complex magnet arrangements and significantly higher costs.
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