A study on high performance poly(ether‐ether‐ketone) (PEEK) composites prepared by incorporating aluminum oxide (Al2O3), 0 to 50 wt % by hot compaction at 15 MPa and 350°C was described. Density, thermogravimetric analysis/differential scanning calorimetry, and scanning electron microscopy (SEM) were employed to evaluate their density, thermal stability, crystallinity, and morphology. Experimental density was found higher than theoretical density, which indicates that composite samples are sound. It was found that the addition of micron sized (< 15 μm) Al2O3 increased the peak crystallization temperature by 12°C when compared with neat PEEK with insignificant increase in melting temperature. Half‐time of crystallization is reduced from 2.05 min for the neat PEEK to 1.08 min for PEEK incorporated with 30 wt % Al2O3 because of the strong nucleation effect of Al2O3. The thermal stability of composites in air atmosphere was increased by 26°C. However, thermal stability in nitrogen atmosphere decreases at lower concentration of Al2O3 but increases above 20 wt % of Al2O3. Uniform dispersion of Al2O3 particles was observed in PEEK polymer matrix by SEM. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 4623–4631, 2006
White matter integrity changes with age, with the extent of variation dependent on attributes such as sex and oligodendrocyte health. Quantification of myelin and axonal integrity in healthy people would provide normative values necessary to determine pathology-related tissue characteristics with normal-aging and gender. We assessed white matter integrity with diffusion tensor imaging-based axial and radial diffusivity procedures (3.0-Tesla magnetic resonance imaging), which measure water diffusion parallel and perpendicular to axonal bundles, indicating axonal and myelin status, respectively, using region-of-interest (ROI) analyses, in 34 healthy adults (age, 46.5±6.0 years, 19 male). Sex differences in diffusion values were assessed with two-sample t-tests, and diffusion changes with age using Pearson’s correlations; whole-brain effect sizes were examined with voxel-based procedures. Multiple brain areas showed increased axial and radial diffusivity values reflecting declines in axonal and myelin integrity with age, especially in mid-hippocampal and posterior thalamic areas. However, axonal and myelin integrity increased in insular and occipital cortex projections with maturity. Females showed reduced fiber and myelin integrity in substantially more structures than males, and included limbic, basal ganglia, pontine, and cerebellar sites. A minority of structures, confined to cerebellar, temporal, and frontal cortices, showed reduced fiber and myelin integrity with age in males over females. Whole-brain effect sizes in diffusion values between sexes and age-related changes showed findings parallel to ROI analyses. The structural differences mandate partitioning of sex and age in adult white matter pathology assessment, and likely contribute to sex-based physiological and behavioral dysfunction in aging and in multiple pathologies.
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