No abstract

The synthesis, characterization, electrochemical, photophysical, and photochemical properties of two hexanuclear mixed-valence compounds are reported. Each supramolecular species consists of two cyano-bridged [(NC)(5)Fe(II)-CN-Pt(IV)(NH(3))(3)L-NC-Fe(II)(CN)(5)] triads that are linked to each other through a Pt(IV)-L-Pt(IV) bridge, where L = 4,4'-dipyridyl (bpy) or 3,3'-dimethyl-4,4'-dipyridyl (dmb). The major difference between the two compounds is the electronic nature of the bridging ligand between the two Pt atoms. Both species exhibit a broad Fe(II) --> Pt(IV) intervalent (IT) absorption band at 421 nm with an oscillator strength that is approximately four times that for [(NC)(5)Fe(II)-CN-Pt(IV)(NH(3))(5)] and twice that for [(NC)(5)Fe(II)-CN-Pt(IV)(NH(3))(4)-NC-Fe(II)(CN)(5)].(4-) When L = bpy, the resonance Raman spectrum obtained by irradiating the IT band at 488 nm exhibits several dipyridyl ring modes at 1604, 1291, and 1234 cm(-1) which are not present in the spectrum when L = dmb. In addition, femtosecond pump-probe spectroscopy performed at 400 nm yields a transient bleach of the IT absorption band with a single exponential decay of 3.5 ps for L = bpy, compared with only 1.8 ps for L = dmb and 2.1 ps for [(NC)(5)Fe(II)-CN-Pt(IV)(NH(3))(4)-NC-Fe(II)(CN)(5)].(4-) Last, prolonged irradiation of the complexes at 488 nm leads to the formation of 4 equiv of ferricyanide with a quantum efficiency of 0.0014 for L = bpy and 0.0011 for L = dmb. The transient absorption, resonance Raman, and photochemical data suggest that the degree of excited electronic coupling in these compounds is tunable by changing the electronic nature of the Pt-L-Pt bridging ligand.

No abstract

Noise and vibration of electrical machines is a major concern. Changes in the machine design to improve its efficiency can lead to unacceptable vibrations. Tools to predict its vibratory and acoustic performance at the design stage need to be developed. An improved finite element model has been developed to analyse the vibration behaviour of a permanent magnet synchronous motor (PMSM) using the finite element software ABAQUS. All components and subsets of the machine have been modelled and validated by experimental modal analysis (EMA) performed on them. Some modelling issues have been overcome so that an accurate enough model has been reached. The laminated stator, as it is formed by a pack of several steel sheets, has been treated as an orthotropic material and windings have been considered a solid orthotropic part as well. The rotor-shaft assembly has also been verified by EMA. The bearings that join the rotor to the assembly of the stator have been represented by radial springs. The electromagnetic forces are applied to the whole machine model in order to obtain the vibration response. These forces are obtained from the magnetic air-gap flux density which has been obtained with a 2D finite element model developed by FLUX. Finally, the vibration response has been used to calculate the radiated noise with an acoustic model developed in LMS

Influence of manufacturing tolerances and eccentricities on the unbalanced magnetic pull in permanent magnet synchronous motors," 2020 International Conference on Electrical Machines (ICEM), 2020, pp. 1363-1369.