Zinc ferrite ZnFe2O4 both in the micro and nano scale is widely used in various fields. The article discusses the structure of this compound and its properties in the nanoscale, which is clearly different from those which the ferrite shows in the microscale. The properties of dust generated electric arc furnace, which can contain up to 40% zinc, substantially in the form of ZnFe2O4 are disscused here. Specific properties (electric, magnetic, thermal) of zinc ferrite nanoparticles determine the very wide possibilities of their use, inter alia as catalysts, absorbents, gas sensors, and a tool to combat cancer.
The article presents the results of the investigation of changes in the chemical and mineralogical composition of slag during steel production in a blown oxygen converter. This process was monitored using the slag samples that were collected during the period when oxygen blowing into an oxygen converter was interrupted. The slag samples were collected after 150 s (2.5 min), then after 5, 8, 11, and 24 min of oxygen blowing, and in minute 27 when oxygen blowing was terminated. The sampling was carried out within five consecutive melting processes. The article presents and documents the changes in the contents of CaO, CaO (free), Fe (total), FeO, SiO2, and in the basicity of the slag during oxygen blowing. It also provides the characteristics of individual structural components formed during oxygen blowing and a detailed description of the lime assimilation process, including the formation of the final structure of the slag, consisting of dicalcium silicate (2CaO·SiO2), tricalcium silicate (3CaO·SiO2), RO-phase, and calcium ferrites (2CaO·Fe2O3). The results of the investigation of the changes in the chemical composition of the slag during oxygen blowing in an oxygen converter were compared with the changes in the structural composition of the slag.
Modern steel plants produce today a large portfolio of various steel grades, many for end-uses demanding high quality. In order to utilize the maximum productivity of the continuous-casting machine, it is sometimes necessary to cast steel grades with different chemical compositions in one sequence. It is important, therefore, to know the possibilities of a specific continuous-casting machine to make the Intermix connections as short as possible. Any interference with established procedures may, however, have a negative impact on the cleanliness of the cast steel. Using physical and numerical simulation tools, it was found that reducing the steel level in the tundish during the exchange of ladles makes it possible to shorten the transition zone. However, when the steel level is reduced, the flow of steel is impaired, which can have a negative effect on the cleanliness of the cast steel and, in extreme cases, may even lead to entrapment of slag in the mold. The cleanliness of cast steel was evaluated using one of the most advanced tools for automatic steel cleanliness evaluation, AZtecFeature (Oxford Instruments, Abingdon, UK), which enables determination of the type, size, distribution, and shape, as well as the chemical composition, of individual types of non-metal inclusions.
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