A boron-capped tris-dioximate iron(II) bis-macrocyclic clathrochelate with annulated dimethylquinoxaline heterocycle has been synthesized. The compound has been characterized with single-crystal X-ray diffraction, multinuclear NMR, IR, UV-vis spectrometry, CV and spectroelectrochemistry. The clathrochelate is capable of ligand-centered two-electron reversible reduction coupled with electrochromism (in solution and thin film).Keywords: Macrocyclic compounds, clathrochelates, iron complexes, ligand reactivity, electrochromism.синтез, строение и (спектро)электрохимическое исследование электрохромного клатрохелата железа(II) с модифицированными редокс -свойствами
Macrobicyclic iron(II) tris-dioximate with two inherent amino groups undergoes electrophilic addition with 1,10-phenanthroline-5,6-dione and phenanthrene-9,10-Ключевые слова: Макроцикличес кие соединения, клатрохелаты, реакционная способность лигандов, электрофильное присоединение.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.