This paper presents the results of a study of the strength and thermophysical properties of the composite material graphene nanoplatelets (GNP)–nitrile butadiene rubber (NBR) (GNP@NBR). High-quality GNP were massively produced by self-propagating high-temperature synthesis (SHS) method. It was found that the introduction of GNP in concentrations up to 6 wt.% leads to an increase in tensile strength up to 62%, resistance to tearing up to 64% thermal conductivity up to 2. The use of GNP allowed increasing the maximum operating temperature of the NBR to 125℃. Also, GNP@NBR composite showed an exceptional improvement in antifriction properties – it drops more than twice the coefficient of friction on steel under loads to 500 Newtons.
A quantitative method is proposed to determine Stone–Wales defects for 1D and 2D carbon nanostructures. The technique is based on the diene synthesis reaction (Diels–Alder reaction). The proposed method was used to determine Stone–Wales defects in the few-layer graphene (FLG) nanostructures synthesized by the self-propagating high-temperature synthesis (SHS) process in reduced graphene oxide (rGO) synthesized based on the method of Hammers and in the single-walled carbon nanotubes (SWCNT) TUBAL trademark, Russia. Our research has shown that the structure of FLG is free of Stone–Wales defects, while the surface concentration of Stone–Wales defects in TUBAL carbon nanotubes is 1.1 × 10−5 mol/m2 and 3.6 × 10−5 mol/m2 for rGO.
For the first time, few-layer graphene (FLG) nanosheets were synthesized by the method of self-propagating high-temperature synthesis (SHS) from biopolymers (glucose, starch, and cellulose). We suggest that biopolymers and polysaccharides, particularly starch, could be an acceptable source of native cycles for the SHS process. The carbonization of biopolymers under the conditions of the SHS process was chosen as the basic method of synthesis. Under the conditions of the SHS process, chemical reactions proceed according to a specific mechanism of nonisothermal branched-chain processes, which are characterized by the joint action of two fundamentally different process-accelerating factors—avalanche reproduction of active intermediate particles and self-heating. The method of obtaining FLG nanosheets included the thermal destruction of hydrocarbons in a mixture with an oxidizing agent. We used biopolymers as hydrocarbons and ammonium nitrate as an oxidizing agent. Thermal destruction was carried out in SHS mode, heating the mixture in a vessel up to 150–200 °C at a heating speed of 20–30 °C/min and keeping at this temperature for 15–20 min with the discharge of excess gases into the atmosphere. A combination of spectrometric research methods, supplemented by electron microscopy data, has shown that the particles of the carbonated product powder in their morphometric and physical parameters correspond to FLG nanosheets. An X-ray diffraction analysis of the indicated FLG nanosheets was carried out, which showed the absence of formations with a graphite crystal structure in the final material. The surface morphology was also studied, and the IR absorption features of FLG nanosheets were analyzed. It is shown that the developed SHS method makes it possible to obtain FLG nanosheets with linear dimensions of tens of microns and a thickness of not more than 1–5 graphene layers (several graphene layers).
The technogenic human activities associated with the operation of nuclear power facilities lead to the contamination of natural water bodies and soils with radioactive substances, including heavy radionuclides, such as uranium and thorium. Purification of natural water bodies is a pressing
environmental issue. A study of the adsorption capacity for heavy U238 and Th232 radionuclides by the samples of new carbon nanomaterials was conducted. Nanocarbon materials was synthesized based on vegetal polymers, such as technical lignin, starch and from lignocellulosic
material—the bark. It was established that the investigated samples have different sorption indices in relation to radionuclides, which is determined by their chemical composition, as well as by the surface-capillary properties of carbonized materials. It is shown that the content of
mobile and fixed forms of radionuclides on the investigated sorbents are significantly different. High sorption capacity of the carbonated lignin sample with respect to uranium are shown. A sample of nanocarbon materials synthesized based on the lignocellulosic complex of the bark exhibits
high sorption properties in relation to thorium. The possibility of using the carbonic nanomaterial as the sorbents of radionuclides is shown.
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