The deep waters of the western Mediterranean are known to have an almost constant trend towards higher salinity and temperature values since the 1950s. Recent observations have shown an acceleration of this tendency, which has been attributed by some authors to the effect of the propagation of the signal of the Eastern Mediterranean Transient, from east to west. From 2004 to 2006 five basin‐scale oceanographic cruises evidenced a relevant change in the deep structure of the western Mediterranean. In less than two years almost the whole deep basin has been filled with highly saline and warm new deep water, which substantially renewed the resident deep water. The paper shows evidence of the rapid basin‐wide extension of the event, giving insights into the origin and the propagation of the new deep water towards the basin interior and showing the evolution of the deep characteristics.
Heavy metals such as lead, mercury, cadmium, zinc and copper are among the most important pollutants because of their non-biodegradability and toxicity above certain thresholds. Here, we review methods for sensing heavy metal ions (HMI) in water samples using screenprinted electrodes (SPEs) as transducers. The review (with 107 refs.) starts with an introduction into the topic, and this is followed by sections on (a) mercury-coated SPEs, (b) bismuth-coated SPEs, (c) gold-coated SPEs (d) chemically modified and non-modified carbon SPEs, (e) enzyme inhibition-based SPEs, and (f) an overview of commercially available electrochemical portable heavy metal analyzers. The review reveals the significance of SPEs in terms of decentralized and of in situ analysis of heavy metal ions in environmental monitoring.
During winter 2012–2013, open‐ocean deep convection which is a major driver for the thermohaline circulation and ventilation of the ocean, occurred in the Gulf of Lions (Northwestern Mediterranean Sea) and has been thoroughly documented thanks in particular to the deployment of several gliders, Argo profiling floats, several dedicated ship cruises, and a mooring array during a period of about a year. Thanks to these intense observational efforts, we show that deep convection reached the bottom in winter early in February 2013 in a area of maximum 28 ± 3
109normalm2. We present new quantitative results with estimates of heat and salt content at the subbasin scale at different time scales (on the seasonal scale to a 10 days basis) through optimal interpolation techniques, and robust estimates of the deep water formation rate of 2.0
±0.2 Sv. We provide an overview of the spatiotemporal coverage that has been reached throughout the seasons this year and we highlight some results based on data analysis and numerical modeling that are presented in this special issue. They concern key circulation features for the deep convection and the subsequent bloom such as Submesoscale Coherent Vortices (SCVs), the plumes, and symmetric instability at the edge of the deep convection area.
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