Rare-earth nickelates form an intriguing series of correlated perovskite oxides. Apart from LaNiO3, they exhibit on cooling a sharp metal-insulator electronic phase transition, a concurrent structural phase transition, and a magnetic phase transition toward an unusual antiferromagnetic spin order. Appealing for various applications, full exploitation of these compounds is still hampered by the lack of global understanding of the interplay between their electronic, structural, and magnetic properties. Here we show from first-principles calculations that the metal-insulator transition of nickelates arises from the softening of an oxygen-breathing distortion, structurally triggered by oxygen-octahedra rotation motions. The origin of such a rare triggered mechanism is traced back in their electronic and magnetic properties, providing a united picture. We further develop a Landau model accounting for the metal-insulator transition evolution in terms of the rare-earth cations and rationalizing how to tune this transition by acting on oxygen rotation motions.

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SignificanceCorrelated transition metal oxide perovskites receive a lot of attention due to their unique physical properties, which are largely driven by distortion of the BO6 octahedral network. In bulk, the control of the octahedral network is normally obtained by cation substitutions in a random alloy. Similar to the charge donors in semiconductors, cation substitutions will introduce scattering and disorder. The development of artificial heterostructures offers unprecedented opportunities to lattice engineering to achieve desired properties. In this work, we demonstrated a structural analogue of modulation doping in nickelate heterostructures through the interfacial transfer of tilt patterns. Modulation tilt control was used to remotely control the Ni–O bonds in the compound SmNiO3 and thereby its critical temperature for optimal optical switching application.

While CaFeO3 exhibits upon cooling a metal-insulator transition linked to charge ordering, SrFeO3 and BaFeO3 keep metallic behaviors down to very low temperatures. Moreover, alkaline-earth ferrites do not seem prone to orbital ordering in spite of the d 4 formal occupancy of Fe 4+ . Here, from first-principles simulations, we show that the metal-insulator transition of CaFeO3 is structurally triggered by oxygen rotation motions as in rare-earth nickelates. This not only further clarifies why SrFeO3 and BaFeO3 remain metallic but allows us to predict that an insulating charge-ordered phase can be induced in SrFeO3 from appropriate engineering of oxygen rotation motions. Going further, we unveil the possibility to switch from the usual charge-ordered to an orbital-ordered insulating ground state under moderate tensile strain in CaFeO3 thin films. We rationalize the competition between charge and orbital orderings, highlighting alternative possible strategies to produce such a change of ground state, also relevant to manganite and nickelate compounds.

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Herein, we disclose a metal-free novel approach for the synthesis of N-( -substituted)alkyl sulfoximines/sulfonimidamides via one-pot multicomponent Petasis reactions of aryl boronic acids, ortho-hydroxyarylaldehydes and sulfoximines/sulfonimidamides in moderate to very...

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Herein, we have reported a metal-free, mild, and novel protocol for the synthesis of various triarylmethanes (TRAMs) in moderate to good yields via the reactions of aryl boronic acids and ortho-hydroxyarylaldehydes in the presence of stoichiometric amounts of Et3N in dichloroethane at 80 °C. Additionally, the synthetic utilities of few synthesized TRAMs were proven by carrying out bromination on the −OH-containing aryl part and followed by functionalization of bromine through a palladium-catalyzed Suzuki–Miyaura cross-coupling reaction with arylboronic acids in good yields. The −OH group was also alkylated and arylated through simple alkylation and Chan–Lam reaction, respectively.