The kinetics and mechanism of aerobic photooxidation of sulfides in the presence of a series of electron-rich and electron-deficient porphyrins immobilized on Amberlyst 15 nanoparticles in the form of porphyrin diacids are reported.
Immobilization of porphyrins on solvent-induced Amberlyst-15 nanoparticles led to the formation of novel porous porphyrinic photosensitizers with high photocatalytic activity towards the aerobic oxidation of olefins in acetonitrile.
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