Perhaps as much as 50% of the oil-in-place in carbonate formations around the world is locked away in the easy to bypass microporosity. If some of this oil is unlocked by the improved recovery processes focused on tight carbonate formations, the world may gain a major source of lower-rate power over several decades. Here, we overview the Arab D formation in the largest oil field on earth, the Ghawar. We investigate the occurrence of microporosity of different origins and sizes using scanning electron microscopy (SEM) and pore casting techniques. Then, we present a robust calculation of the probability of invasion and oil saturation distribution in the nested micropores using mercury injection capillary pressure data available in the literature. We show that large portions of the micropores in Arab D formation would have been bypassed during primary drainage unless the invading crude oil ganglia were sufficiently long. We also show that, under prevailing conditions of primary drainage of the strongly water-wet Arab formations in the Ghawar, the microporosity there was invaded and the porosity-weighted initial oil saturations of 60–85% are expected. Considering the asphaltenic nature of crude oil in the Ghawar, we expect the invaded portions of the pores to turn mixed-wet, thus becoming inaccessible to waterflooding until further measures are taken to modify the system’s surface chemistry and/or create substantial local pore pressure gradients.

Improved oil recovery from asphaltenic oil reservoirs may provide the world with a significant source of lower-cost energy over many decades. However, the mechanisms through which the surface-active components in crude oil, such as asphaltenes and organic acids, affect incremental oil production are still unclear. In this study, we investigate crude oil/water interfacial films using shear and dilational rheology for mechanical properties and Fourier-Transform Infrared Spectroscopy (FTIR) to better understand its molecular species present at the interface that contribute to the development of viscoelastic behaviors. Dilational rheology has proven to be more sensitive to early time development of elasticity. In contrast, shear rheology provided more insights regarding the formation of elastic films at the macroscopic scale and late time interfacial changes. The presence of salts such as sodium chloride in the aqueous phase played a critical role in altering the dynamics of both the rheological properties development and the interfacial tension.

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In this paper, the magnetic nanoparticles are injected into a water-oil, two-phase system under the influence of an external permanent magnetic field. We lay down the mathematical model and provide a set of numerical exercises of hypothetical cases to show how an external magnetic field can influence the transport of nanoparticles in the proposed two-phase system in porous media. We treat the water-nanoparticles suspension as a miscible mixture, whereas it is immiscible with the oil phase. The magnetization properties, the density, and the viscosity of the ferrofluids are obtained based on mixture theory relationships. In the mathematical model, the phase pressure contains additional term to account for the extra pressures due to fluid magnetization effect and the magnetostrictive effect. As a proof of concept, the proposed model is applied on a countercurrent imbibition flow system in which both the displacing and the displaced fluids move in opposite directions. Physical variables, including waternanoparticles suspension saturation, nanoparticles concentration, and pore wall/throat concentrations of deposited nanoparticles, are investigated under the influence of the magnetic field. Two different locations of the magnet are studied numerically, and variations in permeability and porosity are considered.

We investigate the formation and properties of crude oil/water interfacial films. The time evolution of interfacial tension suggests the presence of short and long timescale processes reflecting the competition between different populations of surface-active molecules. We measure both the time-dependent shear and extensional interfacial rheology moduli. Late-time interface rheology is dominated by elasticity, which results in visible wrinkles on the crude oil drop surface upon interface disturbance. We also find that the chemical composition of the interfacial films is affected by the composition of the aqueous phase that it has contacted. For example, sulfate ions promote films enriched with carboxylic groups and condensed aromatics. Finally, we perform solution exchange experiments and monitor the late-time film composition upon the exchange. We detect the film composition change upon replacing chloride solutions with sulfate-enriched ones. To the best of our knowledge, we are the first to report the composition alteration of aged crude oil films. This finding might foreshadow an essential crude oil recovery mechanism.