The direct use of ethanol in fuel cells presents unprecedented economic, technical, and environmental opportunities in energy conversion. However, complex challenges need to be resolved. For instance, ethanol oxidation reaction (EOR) requires breaking the rigid C–C bond and results in the generation of poisoning carbonaceous species. Therefore, new designs of the catalyst electrode are necessary. In this work, two trimetallic PdxAgyNiz/C samples are prepared using a facile borohydride reduction route. The catalysts are characterized by X-ray diffraction (XRD), Energy-Dispersive X-ray spectroscopy (EDX), X-ray photoelectron Spectroscopy (XPS), and Transmission Electron Microscopy (TEM) and evaluated for EOR through cyclic voltammetry (CV), chronoamperometry (CA), and electrochemical impedance spectroscopy (EIS). The XRD patterns have shown a weak alloying potential between Pd, and Ag prepared through co-reduction technique. The catalysts prepared have generally shown enhanced performance compared to previously reported ones, suggesting that the applied synthesis may be suitable for catalyst mass production. Moreover, the addition of Ag and Ni has improved the Pd physiochemical properties and electrocatalytic performance towards EOR in addition to reducing cell fabrication costs. In addition to containing less Pd, The PdAgNi/C is the higher performing of the two trimetallic samples presenting a 2.7 A/mgPd oxidation current peak. The Pd4Ag2Ni1/C is higher performing in terms of its steady-state current density and electrochemical active surface area.

The synthesis of palladium-based trimetallic catalysts via a facile and scalable synthesis procedure was shown to yield highly promising materials for borohydride-based fuel cells, which are attractive for use in compact environments. This, thereby, provides a route to more environmentally friendly energy storage and generation systems. Carbon-supported trimetallic catalysts were herein prepared by three different routes: using a NaBH4-ethylene glycol complex (PdAuNi/CSBEG), a NaBH4-2-propanol complex (PdAuNi/CSBIPA), and a three-step route (PdAuNi/C3-step). Notably, PdAuNi/CSBIPA yielded highly dispersed trimetallic alloy particles, as determined by XRD, EDX, ICP-OES, XPS, and TEM. The activity of the catalysts for borohydride oxidation reaction was assessed by cyclic voltammetry and RDE-based procedures, with results referenced to a Pd/C catalyst. A number of exchanged electrons close to eight was obtained for PdAuNi/C3-step and PdAuNi/CSBIPA (7.4 and 7.1, respectively), while the others, PdAuNi/CSBEG and Pd/CSBIPA, presented lower values, 2.8 and 1.2, respectively. A direct borohydride-peroxide fuel cell employing PdAuNi/CSBIPA catalyst in the anode attained a power density of 47.5 mW cm−2 at room temperature, while the elevation of temperature to 75 °C led to an approximately four-fold increase in power density to 175 mW cm−2. Trimetallic catalysts prepared via this synthesis route have significant potential for future development.

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The ideal smart home could be automatically controlled using a variety of electronic tools and devices to perform everyday tasks. Smart home automation is crucially beneficial for human life, particularly when considering those with disabilities, inpatients, and elderly populations. In this paper, applications and systems for smart homes are investigated. During experimentation they were controlled via an Android mobile phone and the Arduino platform. Bluetooth Module HC-06 was used to connect the Arduino Uno R3 with the mobile phone. Five smart home applications were developed to control the lighting and electrical sockets, fan speed, temperature- and humidity-meter display/controls, as well as the fire-alarm and toxic-gas alarm systems. Herein, the definition, the graphical user interface, the required main components, and the control circuit connections are prepared and presented for each application. The graphical user interface was created using the RemoteXY website, which is a reliable website for this purpose. The developed applications were tested, and they were found to work efficiently and correctly. Additionally, this innovative system is both cost-effective and affordable (total cost at the time of development was 110 USD).

Direct ethanol fuel cells (DEFCs) have shown a high potential to supply energy and contribute to saving the climate due to their bioethanol sustainability and carbon neutrality. Nonetheless, there is a consistent need to develop new catalyst electrodes that are active for the ethanol oxidation reaction (EOR). In this work, two C-supported PdIrNi catalysts, that have been reported only once, are prepared via a facile NaBH4 co-reduction route. Their physiochemical characterization (X-ray diffraction (XRD), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), and X-ray photoelectron spectroscopy (XPS)) results show alloyed PdIrNi nanoparticles that are well dispersed (<3 nm) and exist in metallic state that is air-stable apart from Ni and, slightly, Pd. Their electrocatalytic activity towards EOR was evaluated by means of cyclic voltammetry (CV) and chronoamperometry (CA). Even though the physiochemical characterization of PdIrNi/C and Pd4Ir2Ni1/C is promising, their EOR performance has proven them less active than their Pd/C counterpart. Although the oxidation current peak of Pd/C is 1.8 A/mgPd, it is only 0.48 A/mgPd for Pd4Ir2Ni1/C and 0.52 A/mgPd for PdIrNi/C. These results were obtained three times and are reproducible, but since they do not add up with the sound PdIrNi microstructure, more advanced and in situ EOR studies are necessary to better understand the poor EOR performance.

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Direct ethanol fuel cells (DEFCs) need newly designed novel affordable catalysts for commercialization. Additionally, unlike bimetallic systems, trimetallic catalytic systems are not extensively investigated in terms of their catalytic potential toward redox reactions in fuel cells. Furthermore, the Rh potential to break the ethanol rigid C-C bond at low applied potentials, and therefore enhance the DEFC efficiency and CO2 yield, is controversial amongst researchers. In this work, two PdRhNi/C, Pd/C, Rh/C and Ni/C electrocatalysts are synthesized via a one-step impregnation process at ambient pressure and temperature. The catalysts are then applied for ethanol electrooxidation reaction (EOR). Electrochemical evaluation is performed using cyclic voltammetry (CV) and chronoamperometry (CA). Physiochemical characterization is pursued using X-ray diffraction (XRD), transmission electron microscope (TEM), energy-dispersive X-ray spectroscopy (EDX) and X-ray photoelectron spectroscopy (XPS). Unlike Pd/C, the prepared Rh/C and Ni/C do not show any activity for (EOR). The followed protocol produces alloyed dispersed PdRhNi nanoparticles of 3 nm in size. However, the PdRhNi/C samples underperform the monometallic Pd/C, even though the Ni or Rh individual addition to it enhances its activity, as reported in the literature herein. The exact reasons for the low PdRhNi performance are not fully understood. However, a reasonable reference can be given about the lower Pd surface coverage on both PdRhNi samples according to the XPS and EDX results. Furthermore, adding both Rh and Ni to Pd exercises compressive strain on the Pd lattice, noted by the PdRhNi XRD peak shift to higher angles.