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Summary A device based on perovskite and silicon tandem solar cells is considered as an interesting route to improve cell efficiency further the limit of single junction by keeping the reasonable cost of production. Here, we assess the device performances of CH3NH3PbI3 perovskite as top sub‐cells in tandem solar cells in association with traditional crystalline silicon heterojunction solar cells of various configurations such as monolithic two terminals, four terminals mechanically stacked, and four‐terminal optically coupled perovskite/Si tandem solar cells. Our simulation findings highlight that the suggested architecture design increases the device performance by optimizing the thickness of perovskite. Furthermore, the optimal doping concentration of perovskite (1018 cm−3) has contributed to achieve high tandem efficiencies of various device configurations.

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Summary Mixed cation perovskite type materials have recently shown considerable potential in high‐efficiency single‐ and multi‐junction solar cell devices. However, the operating principles of multiple cation‐based perovskite solar cells are currently poorly understood. Furthermore, the photovoltaic performances of mixed cations‐based perovskites solar cells are investigated using device simulator program. Inorganic TiO2 and Cu2O were used as electron transport layer and hole transport layer, respectively, because of their better performance. The impact of thickness, doping concentration and density of defect is examined using on the device performance. In addition, the effect of band offsets on performance was also investigated through altering the electron affinity of interface layers. Our calculated results reveal that a 700 nm absorber thickness is appropriate for a good solar cell device. Furthermore, impressive cell efficiency findings were obtained by adjusting defect density (1015‐1016 cm−3) of the mixed perovskite active layer. The optimum conduction and valence band offsets, respectively, were determined to be 0.1 to 0.4 eV and 0.1 to 0.1 eV, allowing for a good performance of mixed perovskite devices. As an alternative to typical halide perovskite solar cells, our findings can be utilized to design and construct efficient mixed cations perovskite solar cell devices.