Adhesives are substances that increase the surface adhesion of bonded items. Unfortunately, they also emit volatile organic compounds (VOCs) which negatively impact upon human and animal health. VOCs have carcinogenic and mutagenic properties and can cause migraines, irritation to the eyes, nasal passages, mouth, and lungs, and respiratory problems. Wastewater from adhesive production is characterized by high levels of pollutants and contains high concentrations of compounds including formaldehyde that are toxic to water biocenoses. Moreover, its purification causes many problems and requires the application of specific methods. This review presents data concerning the toxicity and ecotoxicity of selected adhesives components. VOC emission rates from adhesives and wooden construction elements with adhesives are also discussed and assessed. Current knowledge on the treatment methods for wastewater containing adhesive components is reviewed. Finally, the treatment and disposal methods for solid wooden waste containing adhesives are also analyzed and discussed.
In the present study, we examined how the active aluminum nano‐oxide in the gamma form used as a neutral carrier for the nanoparticles of various metals (as Ag, Pr) affected their toxic behavior. Our experiments have shown that exposure to metal nanoparticles can be reduced by binding the nanoparticles to alumina nanoparticles and the aluminum nano‐oxide is suitable to function as the nano‐stabilizer for the Ag and Pr nanoparticles. We have managed to manufacture new alumina‐stabilized silver and praseodymium nanoparticles using dry sol‐gel method that are not phyto‐ and eco‐toxic.
The current study presents results concerning the effect of a static magnetic field (SMF) on synthetic wastewater biodegradation by activated sludge and on dehydrogenase activity of microorganisms of activated sludge. The highest process efficiency was obtained for a SMF of 0.0075 T among the tested magnetic flux density values of 0.005-0.14 T. Decrease in COD was 25% higher for the bioreactor exposed to SMF compared with control experiments. The positive effect of SMF 0.0075-0.0080 T was confirmed in experiments on the dehydrogenase activity of activated sludge. It was also shown that a SMF of 0.007 T increased p-nitroaniline removal from wastewater and influenced the recombination frequency in a streptomycin-resistant bacteria strain of Eschercihia coli.
A laboratory scale sequencing batch reactor (SBR), fed with synthetic wastewater containing a mixture of organic compounds, was operated for nearly six months. Despite maintaining the same operational conditions, a deterioration of enhanced biological phosphorus removal (EBPR) occurred after 40 days of SBR operation. The Prel/Cupt ratio decreased from 0.28 to 0.06 P-mol C-mol−1, and C requirements increased from 11 to 32 mg C h−1 g−1 of mixed liquor suspended solids. A FISH analysis showed that the percentage of Accumulibacter in an overall community of polyphosphate accumulating organisms (PAOs) and glycogen accumulating organisms (GAOs) dropped from 93% to 13%. An increase in abundance of Gammaproteobacteria (from 2.6% to 22%) and Alphaproteobacteria (from 1.8% to 10%) was observed. The number of Competibacter increased from 0.5% to nearly 9%. Clusters 1 and 2 of Defluviicoccus-related GAOs, not detected before deterioration, constituted 35% and 27% of Alphaproteobacteria, respectively. We concluded that lab-scale experiments should not be extended implicitly to full-scale EBPR systems because some bacterial groups are detected mainlyin lab-scale reactors. Well-defined, lab-scale operational conditions reduce the number of ecological niches available to bacteria.
A one-step technological system containing activated sludge fed with synthetic domestic wastewater was applied to treat waste air polluted with tetrachloroethene (PCE). In the first stage of the experiment, air passed through a bioscrubber; in the second and third stages, it passed through the bioreactor containing activated sludge and bacteria immobilised in oak chips. These bacteria are active in PCE biodegradation. Process efficiency in the final stage of the experiment was high; the elimination capacity was 0.23 g m h with the PCE mass loading rate of 0.58 g m h. It has been shown that in the activated sludge bioreactor, bacteria adapted to PCE biodegradation and the wood chips protected microorganisms from the toxic effects of pollution. The dominant strains of bacteria immobilised in wood chips have been identified. Most of them were Gram-negative rods - Pseudomonas aeruginosa, Pseudomonas putida, Ralstonia pickettii and Ochrobactrum anthropii. Only one strain was Gram-positive and of cylindrical shape. The results of the study indicate the potential of immobilised bacteria capable of degrading chlorinated aliphatic hydrocarbons for the air and wastewater treatment. The low cost of the treatment process is an advantage.
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